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CAS No. : | 652-37-9 | MDL No. : | MFCD00022832 |
Formula : | C9H10N4O4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | HCYFGRCYSCXKNQ-UHFFFAOYSA-N |
M.W : | 238.20 | Pubchem ID : | 69550 |
Synonyms : |
Theophylline-7-acetic Acid; Theophyllineacetic Acid; Carboxymethyltheophylline
|
Chemical Name : | 2-(1,3-Dimethyl-2,6-dioxo-1,2,3,6-tetrahydro-7H-purin-7-yl)acetic acid |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P233-P260-P261-P264-P270-P271-P280-P301+P312-P302+P352-P304-P304+P340-P305+P351+P338-P312-P321-P330-P332+P313-P337+P313-P340-P362-P403-P403+P233-P405-P501 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N-ethyl-N,N-diisopropylamine; HATU; In N,N-dimethyl-formamide; at 20℃; for 2h; | To a solution of acid in DMF were added HATU5 DIEA, and aniline in that order. The reaction mixture was stirred for 2hr at room temperature. [00316] After the reaction was complete (LC-MS and TLC)5 the compound was purified by prep-HPLC (250mg). Compound 24 was characterized by 1H NMR5 LC-MS and HPLC. 1H NMR (CDC13), delta: 9.25 (s, IH), 7.77 (s5 IH), 7.15 (t, J=8.14 Hz5 IH)5 7.05 (s, IH)5 6.74-6.80 (m, IH)5 6.46-6.53 (m5 IH), 4.95 (s5 2H)5 3.61 (s, 3H), 3.46 (s, 3H), 2.93 (s, 6H)5 1.59 (s, 3H). LC-MS5 (M+l), 357. HPLC (>;95%, retention time, 5.79 min). |