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CAS No. : | 65-23-6 | MDL No. : | MFCD00006335 |
Formula : | C8H11NO3 | Boiling Point : | - |
Linear Structure Formula : | C5HN(CH3)(OH)(CH2OH)2 | InChI Key : | LXNHXLLTXMVWPM-UHFFFAOYSA-N |
M.W : | 169.17 | Pubchem ID : | 1054 |
Synonyms : |
Pyridoxol;Vitamin B6;Gravidox
|
Chemical Name : | (5-Hydroxy-6-methylpyridine-3,4-diyl)dimethanol |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | In water; isopropyl alcohol; at 20 - 35℃; | Example 3Preparation of pyridoxine, (S)-oxo-2-piperidine carboxylate (Salt IIId)169.2 mg of pyridoxine free base (1 mmol) and 143.1 mg of (S)-oxo-2-piperidine carboxylic acid (1 mmol) (Aldrich) were weighed into a vial and mixed with about 0.2 mL of a solution of isopropyl alcohol containing 4.4percent water.The mixture was heated in the closed vial to a temperature of about 35° C.The mixture was gradually cooled to room temperature overnight.Then, about 2.5 mL of isopropyl alcohol was added under boiling to give a clear solution, and the solution was left to cool to room temperature.Diethyl ether was added and the mixture was maintained at a temperature of about -18° C. to afford crystallization.The crystals were obtained by filtration, washed with cold isopropyl alcohol and dried to yield 270 mg of Salt IIId in 86percent yield.1H NMR (D2O), delta ppm: 1.1 (m, 2H), 1.7 (m, 1H), 2.0 (m, 1H), 2.3 (t, 2H), 2.5 (s, 3H), 3.9 (m 1H), 4.7 (s, 2H), 4.9 (s, 2H), 8.0 (s, 1H). |
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