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CAS No. : | 637-69-4 | MDL No. : | MFCD00008619 |
Formula : | C9H10O | Boiling Point : | - |
Linear Structure Formula : | CH3O(C6H4)CHCH2 | InChI Key : | UAJRSHJHFRVGMG-UHFFFAOYSA-N |
M.W : | 134.18 | Pubchem ID : | 12507 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P210-P280-P370+P378-P403+P235-P501 | UN#: | N/A |
Hazard Statements: | H227-H315 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
38% | With tris[2-phenylpyridinato-C2,N]iridium(III); dipotassium peroxodisulfate; copper(II) bis(trifluoromethanesulfonate); In acetonitrile; at 20℃; for 12h;Inert atmosphere; Schlenk technique; Sealed tube; | To the Schlenk sealed reactor was added p-methoxystyrene (0.2 mmol) of formula I-1,7-methoxycarbonylindole (1 mmol, 5 equivalents), Cu(OTf) 2 (0.02 mmol, 10 molpercent), Ir(ppy) 3 (0.02 mmol, 10 molpercent), K2S2O8 (Formula II-7) 0.4 mmol, 2 eq.), and MeCN (2 mL), then argon-protected and stirred at room temperature for 12 hours. After the reaction was completed by TLC or GC-MS, the solvent was evaporated under reduced pressure and the residue was applied to the column. Chromatography (the eluent is n-hexane / ethyl acetate) affords the desired product of formula III-12. The yield was 38percent. |