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CAS No. : | 50548-45-3 | MDL No. : | MFCD00094238 |
Formula : | C12H7BrO | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | WUYYVOWEBMOELQ-UHFFFAOYSA-N |
M.W : | 247.09 | Pubchem ID : | 190542 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95% | With sodium hydride; In N,N-dimethyl-formamide; at 0 - 100℃; for 1.33333h; | General procedure: Compound A-2 (40.0 g, 132.7 mmol) was dissolved in distilled dimethylformamide (400 mL). It cooled to 0 ,Sodium hydride (3.5 g, 145.9 mmol) was slowly added dropwise thereto. The mixture was stirred for 20 minutes and then at 100 ° C for 1 hour. After completion of the reaction, the reaction mixture was cooled to room temperature,Ethanol (100 mL) was slowly added.The mixture was distilled under reduced pressure, and the resulting mixture was extracted with chloroform,And recrystallized from ethyl acetate to obtain Compound A-3 (30.3 g, yield 81percent). |
95% | With sodium hydride; In N,N-dimethyl-formamide; at 0 - 100℃; for 1.3h; | General procedure: Compound A-2 (40.0 g, 132.7 mmol) was dissolved in distilled dimethylformamide (400 mL)Respectively. It cooled to 0 , sodium hydride here(3.5 g, 145.9 mmol) was slowly added dropwise.Stir for 20 minutes and then stir at 100 for 1 hour. After the reaction was completed, the reaction mixture was cooled to room temperature, and ethanol (100 mL) was slowly added thereto. The mixture was vacuum distilled, and the resulting mixture was recrystallized from chloroform and ethyl acetate to obtain Compound A-3 (30.3 g, yield 81percent)It was obtained. |
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