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CAS No. : | 3011-34-5 | MDL No. : | MFCD00007117 |
Formula : | C7H5NO4 | Boiling Point : | No data available |
Linear Structure Formula : | C6H3OHNO2CHO | InChI Key : | YTHJCZRFJGXPTL-UHFFFAOYSA-N |
M.W : | 167.12 | Pubchem ID : | 18169 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sodium carbonate; In N-methyl-acetamide; | Example 48 (3-Nitro-4-methoxy)benzaldehyde 3-Nitro-4-hydroxybenzaldehyde (1.37 g, 8.20mol) was dissolved in dimethylformamide and methyl iodide (2.55 mL, 41.0 mmol) and sodium carbonate (1.74 g, 164 mmol) were added. The reaction mixture was stirred for 20 hours at ambient temperature and then poured into water. The solid product (1.10 g, 74.0%) was filtered, mp 82 C. 1 H NMR (CDCl3): d, 9.94 (s,1H), 8.37 (d, 1H), 8.11 (dd,1H), 7.25 (d,1H), 4.07 (s,3H). MS (DCl): 182 (MH+). C8 H7 NO4. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Example 225 3-(4-Hydroxy-3-nitro-benzylamino)-4-methoxy-N-phenyl-benzamide The title compound has been made using the procedure of Example 50, but using 3-amino-4-methoxy-N-phenyl benzamide and 3-nitro-4-hydroxybenzaldehyde as starting materials, which are commercially available from Aldrich; m.p. 175-176 C. |
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