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CAS No. : | 244-63-3 | MDL No. : | MFCD00004956 |
Formula : | C11H8N2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | AIFRHYZBTHREPW-UHFFFAOYSA-N |
M.W : | 168.19 | Pubchem ID : | 64961 |
Synonyms : |
Norharman; β-Carboline
|
Chemical Name : | 9H-Pyrido[3,4-b]indole |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P280-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | compound 1 (0.50 g, 2 . 98 mmol) and 60% NaH (0.24 g, 5 . 96 mmol) is placed in a round-bottom flask, then 10 mLDMF dissolved, 45 C stirring 2 h after, then the compound 2 (2.81 g, 8 . 94 mmol) is added in the reaction solution, stirring at the room temperature 16 h, TLC detection raw material the basic reaction is complete. Water, extracted with ethyl acetate 3 times, the organic layer by magnesium sulfate drying, the crude product is concentrated after silica gel column chromatography (CH2 Cl2 : CH3 OH=30:1) purification gets yellow solid compound 3 (0.74 g, yield 77%). |
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