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CAS No. : | 23674-20-6 | MDL No. : | MFCD00230983 |
Formula : | C20H13Br | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | WHGGVVHVBFMGSG-UHFFFAOYSA-N |
M.W : | 333.22 | Pubchem ID : | 4155836 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H317-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
46.5% | With potassium phosphate; copper(l) iodide; ethylenediamine; In toluene; at 120℃; for 12h; | After mixing compound A 4.5 g (0.016 mol), 9-bromo-10-phenylanthracene 6.3 g (0.019 mol), CuI 1.5 g (0.008 mol), K3PO4 10.4 g (0.049 mol), ethylenediamine (EDA) 1.1 mL (0.016 mol), and toluene 150 mL, the mixture was heated to 120C, and stirred for 12 hours. After the reaction was completed, the mixture was washed with distilled water, extracted with ethylacetate (EA), the organic layer was dried with MgSO4, the solvent was removed using a rotary evaporator, and the remaining product was separated using a column to obtain compound H-1, 4.0 g (46.5%). Melting point 307C, UV 268 nm (in methylene chloride (MC)), PL 420 nm (in MC), Molecular weight 535.68 |