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CAS No. : | 19575-07-6 | MDL No. : | MFCD00160630 |
Formula : | C11H9NO2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | CILJSZLWPHTUIP-UHFFFAOYSA-N |
M.W : | 187.20 | Pubchem ID : | 421738 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
21% | With ammonium peroxodisulfate; sulfuric acid; silver nitrate; In water; acetonitrile; at 70 - 80℃; for 0.5h; | General procedure: A freshly prepared solution of ammonium persulfate (3 mmol) in water (5 mL) was added drop wise to a mixture of methyl 2-quinolinecarboxylate (2, 1 mmol), silver nitrate (0.6 mmol) and cycloalkylcarboxylic acid (3 mmol) in 10% H2SO4 (4 mL) during 15 min at 70-80 C. The heating source was then removed and the reaction proceeded with evolution of carbon dioxide. After another 15 min, pouring the mixture onto a crushed ice terminated reaction. The resulting mixture was made alkaline with 25% NH4OH solution, and extracted with ethyl acetate (3×50 mL). The combined extract was washed with brine (2×10mL) and dried over Na2SO4. The solvent was removed under reduced pressure to afford oil, which on chromatography over silica gel using EtOAc/hexanes (20:80) afforded 3-10. |
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