Alternatived Products of [ 19227-13-5 ]
Product Details of [ 19227-13-5 ]
CAS No. : | 19227-13-5 |
MDL No. : | MFCD06411167 |
Formula : |
C8H10N2O
|
Boiling Point : |
- |
Linear Structure Formula : | CH3C6H4C(NH2)NOH |
InChI Key : | - |
M.W : |
150.18
|
Pubchem ID : | - |
Synonyms : |
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Application In Synthesis of [ 19227-13-5 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 19227-13-5 ]
- 1
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[ 19227-13-5 ]
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[ 19887-32-2 ]
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ethyl [(S)-1-(3-p-tolyl-1,2,4-oxadiazol-5-yl)-2-phenylethyl]carbamate
[ No CAS ]
- 2
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[ 19227-13-5 ]
-
[ 19887-32-2 ]
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C20H23N3O4
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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|
General procedure: In a sealed tube in amicrowave reactor, 0.8 mmol of L-N-protected amino acid(1-5) and DCC (0.96 mmol, 0.199 g) were dissolved in acetone(1.0 mL) and the mixture was magnetically stirred forapproximately 40 minutes to form the reactive intermediate. Then, 0.8 mmol of aryl amidoxime (a-e) was added, and themixture was homogenized. The acetone was removed inroute evaporator without heating, and H2O (1.0 mL) wasadded to the mixture, which was subjected to microwaveirradiation at 100W power, temperature of 115C, during15 min. Soon after, the reaction crude was dissolved in ethylacetate and washed with water. The organic phase was driedover magnesium sulfate, and the solvent was removed undervacuum. The residue was purified by column chromatographyon silica gel (hexane-ethyl acetate, 7 : 3) to afford pureproducts (1-5a-e). Detailed experimental procedures, 1Hand 13C NMR spectra for all compounds, are available in thesupporting information, ESI (available here). |
- 3
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[ 19227-13-5 ]
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[ 19887-32-2 ]
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ethyl [(S)-1-(3-p-tolyl-1,2,4-oxadiazol-5-yl)-2-phenylethyl]carbamate
[ No CAS ]