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CAS No. : | 156028-26-1 | MDL No. : | MFCD08056065 |
Formula : | C24H4Cl4O6 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | YGRXZLAMYLGXMF-UHFFFAOYSA-N |
M.W : | 530.10 | Pubchem ID : | 12138167 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80.53% | With propionic acid; for 17h;Heating / reflux; | 5. N,N'-Bis(4-bromo-2,6-diisopropylphenyl)-1,6,7,12-tetrachloro-3,4,9,10-tetracarboxylic acid diimide 10 g (0.019 mol) of 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic dianhydride, 24.16 g (0.094 mol) of <strong>[80058-84-0]4-bromo-2,6-diisopropylaniline</strong> and 250 ml of propionic acid are refluxed for 17 hours under argon in a 500 ml one-necked flask and cooled to room temperature, and the solid formed is subsequently filtered off via a D3 glass frit. The residue is washed in portions with 1 1 of water/methanol (1:3) and dried overnight at 75° C. in a vacuum drying oven. Yield: 15.4 g (80.53percent) of orange-red solid Melting point: >300° C. 1H-NMR spectrum (250 MHz, C2D2Cl4, 25° C.): delta (ppm)=8.68 (s, 4H, H-1), 7.28 (s, 4H, H-2), 2.61 (h, 3J=6.4 Hz, 4H, H-3), 1.18 (d, 3J=4.6 Hz, 24 H, H-4) 13C-NMR spectrum (spin echo experiment, 62.5 MHz, THF-d8, 25° C.): delta (ppm)=162.89 (C=O), 149.59 (arom. q), 136.17 (arom q), 133.80 (arom. CH), 132.72 (arom. q), 130.80 (arom. q), 129.60 (arom. q), 128.27 (arom. CH), 125.34 (arom. q), 124.63 (arom. q), 110.21 (arom. q), 30.09 (CHisopropyl) 24.03 (CH3 isopropyl) FD mass spectrum: m/e (u e0-1)=1001.4 (100percent, M+) (calc.: 1001.98) UV spectrum (CHCl3): lambdamax (epsilon)=427 (11078), 488 (33922), 522 nm (49517 1 mol-1 cm-1) IR spectrum: nu=1704 (nuC=O), 1663 (nuC=O), 1585, 1401, 1356, 1301, 1201, 852 cm-1 |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1H-imidazole; at 100℃; for 12h; | To a 100 mL flask 1,6,7,12-tetrachloroperylene tetracarboxylic acid dianhydride 530.1 (5.0 g), <strong>[2734-70-5]2,6-dimethoxyaniline</strong> (3.6 g) and imidazole (20 g) were stirred at 100 C for 12 hours. Thereafter, methanol (200 g) was added thereto, and the formed solid was filtered to obtain a compound represented by the following formula (A-4). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1H-imidazole; at 100℃; for 12h; | To a 100 mL flask 1,6,7,12-tetrachloroperylene tetracarboxylic acid dianhydride (5.0 g), <strong>[6299-67-8]2,3-dimethoxyaniline</strong> (3.6 g) and imidazole (20 g) were stirred at 100 C for 12 hours. Thereafter, methanol (200 g) was added thereto, and the formed solid was filtered to obtain a compound represented by the following formula (A-7). |
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