成人免费xx,国产又黄又湿又刺激不卡网站,成人性视频app菠萝网站,色天天天天

Home Cart 0 Sign in  

[ CAS No. 1530-33-2 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 1530-33-2
Chemical Structure| 1530-33-2
Structure of 1530-33-2 * Storage: {[proInfo.prStorage]}

Please Login or Create an Account to: See VIP prices and availability

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

* Shipping: {[proInfo.prShipping]}

Quality Control of [ 1530-33-2 ]

Related Doc. of [ 1530-33-2 ]

Alternatived Products of [ 1530-33-2 ]
Product Citations

Product Citations

Gethmini Kasunka Jayasekara ;

Abstract: Light-matter interactions can change the physical and chemical properties of a substance. The energy of photons can be used to dissociate the chemical bonds as well as to generate new bonds. The work in this dissertation is an attempt to understand how photon energy governs the formation of new carbon bonds via alkene groups in the presence of copper catalyst. Intermolecular and intramolecular [2+2] photocycloaddition reactions facilitate the generation of cyclobutane moieties which are otherwise difficult to synthesize. Transition metal-based salts are used as catalysts to promote photocycloaddition reactions. The structure and the ring strain of a substrate can affect the reactivity and the rate of the photocycloaddition reactions. In this dissertation chapter 2 focuses on understanding the mechanism of Copper(I)-catalyzed intermolecular [2+2] photocycloaddition reactions. We have used norbornene and cyclohexene as model substrates to explicate the mechanism of the Cu(I)-catalyzed intermolecular photocycloaddition reactions by using Xray and optical transient absorption techniques. The mechanism for norbornene shows an initial metal to ligand charge transfer (MLCT) state which lasts for 18ns prior to reverse electron transfer. Cyclohexene shows a change in metalligand bond strength instead of undergoing charge transfer. The evidence of the change in bond strength is consistent with the proposed idea of Salomon and Kochi for the formation of a more strained trans-cyclohexene intermediate. The work presented in Chapter 3 of this dissertation focuses on understanding the mechanism of Cu(I)-catalyzed intramolecular [2+2] photocycloaddition reactions through the utilization of experimental and theoretical methods. The model substrates used for this study are 1,6-heptadiene, 1,7-octadiene, and 1,8-nonadiene which are linear alkenes with different carbon chain lengths. According to literature, only 1,6-dienes have been shown to undergo Cu(I)-catalyzed [2+2] photocycloaddition reactions. Theoretical DFT/TD-DFT calculations and experimental high energy resolution X-ray absorption spectroscopic studies are done to understand the structurefunctional differences in photoreactive and nonreactive substrates. Based on the correlations observed between structure and photoreactivity, we have modified the structure of non-reactive substrates to adopt photoreactive conformations with steric modifications. Nuclear Magnetic Resonance (NMR) spectroscopy is used to confirm the photoreactivity of the alkene substrates.

Purchased from AmBeed:

Product Details of [ 1530-33-2 ]

CAS No. :1530-33-2 MDL No. :MFCD00064807
Formula : C21H22BrP Boiling Point : No data available
Linear Structure Formula :- InChI Key :HSOZCYIMJQTYEX-UHFFFAOYSA-M
M.W : 385.28 Pubchem ID :2795292
Synonyms :

Safety of [ 1530-33-2 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1530-33-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1530-33-2 ]
Recommend Products
Same Skeleton Products

Technical Information

Historical Records
; ;