Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | ||||||
{[ item.p_purity ]} | {[ item.pr_size ]} | Inquiry |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price) ]} |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate,item.pr_is_large_size_no_price) ]} | {[ item.pr_usastock ]} | in stock Inquiry - | {[ item.pr_chinastock ]} | {[ item.pr_remark ]} in stock Inquiry - | Login | Inquiry |
Please Login or Create an Account to: See VIP prices and availability
CAS No. : | 15028-41-8 | MDL No. : | MFCD00214247 |
Formula : | C5H12ClNO2 | Boiling Point : | No data available |
Linear Structure Formula : | NH2C(CH3)2COOCH3·HCl | InChI Key : | NVWZNEDLYYLQJC-UHFFFAOYSA-N |
M.W : | 153.61 | Pubchem ID : | 13258034 |
Synonyms : |
|
Chemical Name : | H-Aib-OMe.HCl |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | With triethylamine; In ethanol; at 150℃; for 0.5h;Microwave irradiation; | 2-(5-Iodo-3-nitro-pyridin-2-ylamino)-2-methyl-propionic acid methyl ester2-Chloro-5-iodo-3-nitro-pyridine (1.61 g) was dissolved in ethanol. Methyl a- aminoisobutyrate HCl was added (2.4 eq) followed by triethylamine (2.4 eq). The reaction mixture was heated to 1500C in a microwave oven for 30 minutes. The reaction mixture was concentrated to dryness and triturated with H2O. Silica gel chromatography of the resulting brown solid afforded the title compound as a bright yellow crystalline solid (78 % yield based on recovered starting material). M.p. 121-122 0C, 1H-NMR (CDCl3, 400 MHz) delta 1.56 (s, 3H), 1.66 (s, 3H), 3.67 (s, 3H), 8.53 (s, IH), 8.47 (d, J= 2.0 Hz, IH), 8.68 (d, J= 2.3 Hz, IH). |
[ 1363383-31-6 ]
Methyl 3-aminooxetane-3-carboxylate
Similarity: 0.89