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CAS No. : | 149597-91-1 | MDL No. : | MFCD01631990 |
Formula : | C15H15NO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | PECGVEGMRUZOML-CQSZACIVSA-N |
M.W : | 241.29 | Pubchem ID : | 1520861 |
Synonyms : |
|
Chemical Name : | (R)-2-Amino-3,3-diphenylpropanoic acid |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Example 1 (Scheme I):; N-(2-oxo-2-propoxyethyl)-beta-phenyl-D-phenylalanyl-N-r(1-amino-6-isoquinolinyl)methyll- L-prolinamide (1A); A: N-[2-(1 , 1 -Dimethylethoxy)-2-oxoethyll-3-phenyl-D-phenylalanine (a); To a stirred mixture of <strong>[149597-91-1]D-<strong>[149597-91-1]diphenylalanine</strong></strong>, H-D-Dpa-OH, (20.0 g, 82.9 mmol) and potassium carbonate (17.2 g, 125 mmol) in dioxane/water (1 :1 (v/v), 100ml) was added terf-butyl bromoacetate (12.2 ml, 83.0 mmol). After stirring overnight water (100ml) was added and the pH adjusted to 5.5 with 0.5M citric acid solution. The resultant precipitate was filtered off, washed with water then diethyl ether and dried under vacuum to give10.4 g of the title compound ^1 |
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