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[ CAS No. 14473-91-7 ] {[proInfo.proName]}

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Chemical Structure| 14473-91-7

Chemical Structure| 14473-91-7

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Quality Control of [ 14473-91-7 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

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Product Details of [ 14473-91-7 ]

CAS No. :	14473-91-7	MDL No. :	MFCD00004382
Formula :	C₉H₇BrO₂	Boiling Point :	No data available
Linear Structure Formula :	-	InChI Key :	YEMUSDCFQUBPAL-SNAWJCMRSA-N
M.W :	227.05	Pubchem ID :	776461
Synonyms :

Safety of [ 14473-91-7 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P305+P351+P338	UN#:
Hazard Statements:	H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 14473-91-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 14473-91-7 ]

[ 14473-91-7 ] Synthesis Path-Downstream 1~2

1
[ 29608-05-7 ]
[ 14473-91-7 ]
1-(4-(3-bromocinnamoylamino)benzyl)piperidine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With thionyl chloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N-methyl-acetamide; water;	REFERENCE EXAMPLE 49 To 3-bromocinnamic acid (2.0 g) were added thionyl chloride (25 ml) and dimethylformamide (catalytic amount), and the mixture was refluxed for 1.5 hours. The solvent was evaporated, and the residue was dissolved in tetrahydrofuran. The mixture was dropwise added to a suspension of <strong>[29608-05-7]1-(4-aminobenzyl)piperidine</strong> (1.7 g) and diisopropylethylamine (4 ml) in tetrahydrofuran (5 ml) under ice-cooling. Under nitrogen atmosphere, the mixture was stirred at room temperature over night. The solvent was evaporated, and to the residue was added water. The mixture was extracted with ethyl acetate. The organic layer was washed with water and saturated sodium chloride solution, and dried with anhydrous magnesium sulfate. Under reduced pressure, the solvent was evaporated, and the residue was purified with silica gel column (methanol/triethylamine/ethyl acetate) to give crude crystals, which were recrystallized from ethyl acetate-hexane to give 1-(4-(3-bromocinnamoylamino)benzyl)piperidine (1.8 g) as colorless crystals. mp 144-145 C.; 1 H-NMR(delta ppm, CDCl3): 1.37-1.49 (2H, m), 1.52-1.63 (4H, m), 2.34-2.39 (4H, m), 3.45 (2H, s), 6.54 (1H, d, J=15.5 Hz), 7.21-7.33 (3H, m), 7.41-7.57 (5H, m), 7.67 (1H, d, J=15.5 Hz), 7.69 (1H, s). IR(KBr) nu: 3270, 2934, 1663 cm31 1. Anal. for C21 H23 BrN2 O.0.2H2 O: Calcd. C,62.60; H,5.85; N,6.95. Found C,62.67; H,5.79; N,6.93.

Reference： [1]Patent: US6166006,2000,A

2
[ 14473-91-7 ]
[ 30163-20-3 ]

Reference： [1]ChemCatChem,2020,vol. 12,p. 995 - 998

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Technical Information

? Alkyl Halide Occurrence ? Arndt-Eistert Homologation ? Baeyer-Villiger Oxidation ? Barbier Coupling Reaction ? Baylis-Hillman Reaction ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Bucherer-Bergs Reaction ? Clemmensen Reduction ? Corey-Bakshi-Shibata (CBS) Reduction ? Corey-Chaykovsky Reaction ? Fischer Indole Synthesis ? Friedel-Crafts Reaction ? General Reactivity ? Grignard Reaction ? Henry Nitroaldol Reaction ? Hiyama Cross-Coupling Reaction ? Horner-Wadsworth-Emmons Reaction ? Hunsdiecker-Borodin Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Kinetics of Alkyl Halides ? Kumada Cross-Coupling Reaction ? Lawesson's Reagent ? Leuckart-Wallach Reaction ? McMurry Coupling ? Meerwein-Ponndorf-Verley Reduction ? Nomenclature of Ethers ? Passerini Reaction ? Paternò-Büchi Reaction ? Petasis Reaction ? Peterson Olefination ? Pictet-Spengler Tetrahydroisoquinoline Synthesis ? Preparation of Aldehydes and Ketones ? Preparation of Alkylbenzene ? Preparation of Amines ? Preparation of Carboxylic Acids ? Preparation of Ethers ? Prins Reaction ? Reactions of Aldehydes and Ketones ? Reactions of Alkyl Halides with Reducing Metals ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Carboxylic Acids ? Reactions of Dihalides ? Reactions of Ethers ? Reformatsky Reaction ? Robinson Annulation ? Schlosser Modification of the Wittig Reaction ? Schmidt Reaction ? Specialized Acylation Reagents-Ketenes ? Stille Coupling ? Stobbe Condensation ? Substitution and Elimination Reactions of Alkyl Halides ? Suzuki Coupling ? Tebbe Olefination ? Ugi Reaction ? Vilsmeier-Haack Reaction ? Wittig Reaction ? Wolff-Kishner Reduction

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P337 + P313	IF eye irritation persists: Get medical advice/attention.
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H200	Unstable explosive
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