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CAS No. : | 136117-74-3 | MDL No. : | MFCD06739248 |
Formula : | C8H6N2O | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | NVRSZEFZHMVGRS-UHFFFAOYSA-N |
M.W : | 146.15 | Pubchem ID : | 10997174 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P280 | UN#: | N/A |
Hazard Statements: | H302-H317 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55% | [0165] To a solution of methyl imidazo[l,2-a]pyridine-8-carboxylate (1.76 g, 10 mmol) in toluene was added DIBAL (IM/THF, 20 ml) at -78 C dropwise. The mixture was stirred at - 78 C for 1 h, quenched with MeOH (2 mL) and saturated NH4CI solution (50 mL) and warmed up to rt. The mixture was continued to stir at rt for 1 h and diluted with DCM (60 mL). The aqueous layer was extracted with DCM (60 mL) twice. The combined organic layer was dried over MgS04 and concentrate. The residue was purified on silica gel with 10 %MeOH/DCM to give imidazo[l,2-a] pyridine- 8-carbaldehyde (0.8g, 55%). LRMS (M+lf) m/z 147.1. |
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