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CAS No. : | 134979-01-4 | MDL No. : | MFCD11865374 |
Formula : | C6H14ClNO4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | NGPFHPADAGAUDR-UHFFFAOYSA-N |
M.W : | 199.63 | Pubchem ID : | 45789699 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
2.3 g | With hydrogenchloride; In ethyl acetate; at 0℃; | To a 100mL single-neck flask were added 2.4g compound BG06 and 20ml ethyl acetate, after being dissolved, they were cooled down to 0C, into which was added 20 ml HCl/ethyl acetate (7mol/L). After the completion of the reaction under the monitor of TLC, they were concentrated to give 2.3g BG07 as an oil. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
49% | With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20℃; for 16h;Inert atmosphere; | To an oven-dried round bottom flask were added 2-(2-(2-amino-ethoxy)- ethoxy)- acetic acid hydrochloride (32) (1 g, 5.0 mmol), Af, A-di i sopropyl ethyl am i ne (2.62 mL, 15.0 mmol), di-tert-butyl dicarbonate (1.31 g, 6.0 mmol), and CH2CI2 (50 mL) at 0 C under N2. The mixture was vigorously stirred and allowed to warm up to room temperature slowly overnight (16 h). After reaction the insoluble starting material, 32, disappeared. The solvents were evaporated under vacuum and the residue was purified by column chromatography (S1O2, solvent gradient: CH2CI2 to 1 :9 MeOH/CTLCk) to give 33 as a colorless oil (640 mg, 49%). R/(silica gel, 1 :9 MeOH/CH2Cl2) = 0.07; NMR (400 MHz, CDCL): d 5.21 (s, 1H), 4.01 (s, 2H), 3.75-3.63 (m, 4H), 3.55 (t, J= 5.0 Hz, 2H), 3.31 (br q, J= 5.2 Hz, 2H), 1.44 (m, 9H). |
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