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CAS No. : | 10433-52-0 | MDL No. : | MFCD00065936 |
Formula : | C10H13NO3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | IDGQXGPQOGUGIX-SECBINFHSA-N |
M.W : | 195.22 | Pubchem ID : | 112114 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
3 and 4: (Scheme 1): The corresponding O-benzyl protected D- or L-serine 1 or 2 (5.00 g, 25.6 mmol) was added slowly to a suspension of Li-AlH4 (1.46 g, 38.5 mmol) in THF (100 ml). The resulting mixture was heated under reflux for 5 hours and then cooled to 0 C. Excess LiAlH4 was subsequently quenched with 10% NaOH aq. (6 ml) and water (6 ml). The slurry was stirred at ambient temperature for 30 minutes and Boc2O (6.15 g, 28.2 mmol) in dichloromethane (20 ml) was added. The reaction mixture was stirred over night and filtered over a short path of silica. Evaporation of the solvents and recrystallization from MTBE and pentane provided the products 3 or 4 (8.18 g). |
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(S)-Benzyl 2-amino-3-(benzyloxy)propanoate
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