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Postion:Product Catalog >API>Respiratory Drugs>Expectorants>p-Cymene
p-Cymene
  • p-Cymene
  • p-Cymene
  • p-Cymene
  • p-Cymene
  • p-Cymene

p-Cymene NEW

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Package 25KG
Min. Order: 1KG
Supply Ability: 50000KG/month
Update Time: 2023-08-18

Product Details

Product Name: p-Cymene CAS No.: 99-87-6
EC-No.: 202-796-7 Min. Order: 1KG
Purity: 99% Supply Ability: 50000KG/month
Release date: 2023/08/18

CAS:99-87-6
MF:C10H14
MW:134.22
EINECS:202-796-7
Product Categories:Arenes;Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Standard Solutions (VOC);Artemisia vulgaris;Boswellia carterii;Building Blocks;Carthamus tinctorius (Safflower oil);Chamaemelum nobile (Chamomile tea);Chemical Synthesis;Citrus aurantium (Seville orange);Curcuma longa (Turmeric);Elettaria Cardamomum (Cardamom);Ginkgo biloba;Humulus lupulus (Hops);Lavandula angustifolia (Lavendar tea);Melaleuca alternifolia;Nutrition Research;Ocimum basilicum (Basil);Organic Building Blocks;Phytochemicals by Plant (Food/Spice/Herb);s wort);Zingiber officinale (Ginger)
Mol File:99-87-6.mol
Article illustration

p-Cymene Chemical Properties
Melting point -68 °C
Boiling point 176-178 °C(lit.)
density 0.86 g/mL at 25 °C(lit.)
vapor density 4.62 (vs air)
vapor pressure 1.5 mm Hg ( 20 °C)
refractive index n20/D 1.490(lit.)
FEMA 2356 | P-CYMENE
Fp 117 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Liquid
color Clear
OdorMild, pleasant; aromatic, solvent-type.
Odor Threshold0.057ppm
Odor Typeterpenic
explosive limit5.6%
Water Solubility PRACTICALLY INSOLUBLE
Merck 14,2763
JECFA Number1325
BRN 1903377
Stability:Stable. Flammable. Incompatible with strong oxidizing agents, strong acids, strong bases.
InChIKeyHFPZCAJZSCWRBC-UHFFFAOYSA-N
LogP4.1-4.8 at 20℃
CAS DataBase Reference99-87-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-methyl-4-(1-methylethyl)-(99-87-6)
EPA Substance Registry Systemp-Cymene (99-87-6)
p-Cymene Usage And Synthesis
Descriptionp-Cymene is a naturally occurring compound, although it has two further geometric isomers, m-cymene (with meta-substituted alkyl groups) and o-cymene (with ortho-substituted alkyl groups) which do not occur naturally. p-Cymene is related to the monoterpenes. Monoterpenes themselves belong to the “terpenes”, a larger class of organic compounds, which are the most representative components of essential oils. chemical structure of p-cymene, indicating the benzene ring with methyl and isopropyl substitutions.
Article illustration
chemical structure of p-cymene
Chemical Propertiesp-Cymene has a citrusy aroma reminiscent of lemon. It is colorless liquid with a strong, characteristic odor reminiscent of carrot. It tends to darken with aging. It occurs naturally in orange peel oil, mandarin peel oil, satsuma mandarin peel oil, coldpressed lime peel oil, distilled lime peel oil, cinnamon leaf, etc. 4-isopropyltoluene has antimicrobial properties. It is used as a flavor ingredient permitted for direct addition to food for human consumption.
Usesp-Cymene is an alkyl aromatic hydrocarbon mainly used to study oxidation reactions under various conditions to synthesize highly valuable intermediates and building-blocks such as cymene hydroperoxide, 4-methyl acetophenone, 4-isopropyl benzyl alcohol, 4-isopropyl benzaldehyde and 4-isopropyl benzoic acid etc.
Medicinally, p-cymene is used to prevent coughs and eliminate phlegm as well as being a flavouring agent, and being used in the production of fungicides and pesticides. It is considered to be “generally recognised as safe” (GRAS) by the U.S. Food and Drug Administration. Its potential in the prevention of protein glycation mediated diabetic complications has also been confirmed, and it has been suggested as an in vivo antioxidant compound due to its ability to reduce the formation of oxygen and nitrogen reactive species, acting as a potential neuroprotective agent in the brain. Therefore, it could be involved in the treatment of oxidative stress related diseases.
Production Methodsp-cymene is conventionally produced by the Friedel-Crafts alkylation of toluene with isopropanol, or of benzene with methyl or isopropyl halides.
References[1] George A. Burdock, Encyclopedia of Food and Color Additives, Volume 1, 1996
[2] C.F. Bagamboula, M. Uyttendaele and J. Debevere, Inhibitory effect of thyme and basil essential oils, carvacrol, thymol, estragol, linalool and p-cymene towards Shigella sonnei and S. flexneri, Food Microbiology, 2004, vol. 21, 33-42
Chemical Propertiesp-Cymene is a monoterpene that is found in a variety of plants, including C. sativa, and has diverse biological activities, including antimicrobial, anticancer, antioxidant, anti-inflammatory, antinociceptive, and anxiolytic properties.p-Cymene inhibits the growth of S. typhimurium, E. coli, L. monocytogenes, S. epidermidis, and S. aureus with MIC values ranging from 0.266 to 0.608% v/v.It decreases the invasive activity of HT-1080 human fibrosarcoma cells in vitro by 87% when used at a concentration of 600 μM.In mouse hippocampus, p-Cymene (50 mg/kg, i.p.) reduces lipid peroxidation and nitrite content by 65.5 and 71.2%, respectively, and increases superoxide dismutase (SOD) and catalase activities by 22.7 and 119.3%, respectively, compared to vehicle control animals.Formulations containing p-cymene have been used as flavoring agents.
OccurrenceWidespread in nature; reported in the oils of cypress, Artemisia cina Bg., Ceylon cinnamon, boldo leaf, cascarilla, Cuminum cyminum L. and lemon; in the oils for seeds of coriander and Cicuta virosa; in the ether-extracted oils of Monarda fisulosa and Monarda puncata; in the star anise and nutmeg essential oils. Note that p-cymene reported in essential oil may be formed from the conversion of a cyclic terpene; its presence is indicative of aging in lemon essential oil. Reported found in citrus juices and peel oils, guava, papaya, black currant, pineapple, blueberry, blackberry, carrot, tomato, celery seed, cumin seed, mace, ginger, coriander seed, anise, nutmeg, mace, parsley, cardamom, cinnamon root and bark, pepper, peppermint oil, spearmint oil, cassia leaf and Thymus vulgaris.
UsesAs a diluent for lacquers, varnishes, and dyes; in the production of resins; as a component of fragrances; also found as a byproduct in the manufacture of sulfite paper pulp
UsesIt is used in heat-exchange media, metal polishes, and thinners for lacquers/varnishes. Also used to make para-cresol, carvacrol, and synthetic resins. It is also used as a component of commercial terpene solvent mixtures.
PreparationObtained chiefly from the wash water of sulfite paper.
DefinitionChEBI: A monoterpene that is toluene substituted by an isopropyl group at position 4.
Aroma threshold valuesAroma characteristics at 1% EtoH: harsh chemical, woody and terpy-like with an oxidized citrus lemon note. It has spicy nuances reminiscent of cumin, oregano and cilantro
Taste threshold valuesTaste characteristics at 1 to 10 ppm: terpy and rancid with slightly woody, oxidized citrus notes. It has spice nuances of green pepper and oregano.
Synthesis Reference(s)Journal of the American Chemical Society, 95, p. 982, 1973 DOI: 10.1021/ja00784a090
General DescriptionColorless liquid with a mild pleasant odor. Floats on water.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileVigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as CYMENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
Health HazardInhalation causes impairment of coordination, headache. Contact with liquid causes mild irritation of eyes and skin. Ingestion causes irritation of mouth and stomach.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and ExplosibilityFlammable
Chemical ReactivityReactivity with Water: No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety ProfileMildly toxic by ingestion. Humans sustain central nervous system effects at low doses. A skin irritant. Flammable liquid. Explosion Hazard: Slight in the form of vapor. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
MetabolismIn this compound both an isopropyl and a methyl group occur together and the available evidence shows that only the methyl group is oxidized, cumic acid (pisopropylbenzoic acid) and its conjugate (cuminuric acid) being the main metabolites in dogs and in sheep (Williams, 1959). Following inhalation, only a small part is excreted unchanged, the remainder being oxidized to water-soluble metabolites. As early as 1873, Ziegler suggested that the readily oxidized propyl side-chain formed a -COO H group (Browning, 1965): The ultimate product in the case of dogs and sheep is cumic acid, which is probably excreted as a conjugate with glycine (Gerarde, 1960).
Purification MethodsWash p-cymene with cold, conc H2SO4 until there is no further colour change, then repeatedly with H2O, 10% aqueous Na2CO3 and H2O again. Dry it over Na2SO4, CaCl2 or MgSO4, and distil it. Further purification steps include steam distillation from 3% NaOH, percolation through silica gel or activated alumina, and a preliminary reflux for several days over powdered sulfur. Store it over CaH2. [Beilstein 5 IV 1060.]

Packing &shipping&Payment

Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms)1 - 10000>10000
Est. Time(days)5To be negotiated

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Article illustrationCompany information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.

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