- 9-Bromophenanthrene
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- $10.00 / 1kg
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2024-12-20
- CAS:573-17-1
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 20 ton
- 9-Bromophenanthrene
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- $35.00 / 1KG
-
2024-12-20
- CAS:573-17-1
- Min. Order: 1KG
- Purity: 98%
- Supply Ability: 300MT/year
- 9-Bromophenanthrene
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- $0.00 / 25KG
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2024-10-31
- CAS:573-17-1
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 500000kg
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| | 9-Bromophenanthrene Basic information |
| | 9-Bromophenanthrene Chemical Properties |
| Melting point | 60-64 °C (lit.) | | Boiling point | 180-190 °C/2 mmHg (lit.) | | density | 1.4251 (rough estimate) | | refractive index | 1.6404 (estimate) | | Fp | >230 °F | | storage temp. | Sealed in dry,Room Temperature | | solubility | chloroform: 50 mg/mL, clear | | form | Powder | | color | Light yellow | | BRN | 1869927 | | InChI | InChI=1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H | | InChIKey | RSQXKVWKJVUZDG-UHFFFAOYSA-N | | SMILES | C1=C2C(C3C(C(Br)=C2)=CC=CC=3)=CC=C1 | | CAS DataBase Reference | 573-17-1(CAS DataBase Reference) | | NIST Chemistry Reference | Phenanthrene, 9-bromo-(573-17-1) |
| | 9-Bromophenanthrene Usage And Synthesis |
| Description | 9-Bromophenanthrene is a luminescent material that fluoresces at short wavelengths and can be used as a molecular probe to detect the presence of other compounds and the mechanism of reaction, among other things. | | Chemical Properties | light yellow powder. soluble in toluene, and chloroform (50 mg/ml). | | Uses | 9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission. | | Preparation | 9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature. |
| | 9-Bromophenanthrene Preparation Products And Raw materials |
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