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ChemicalBook >> CAS DataBase List >> tert-Butyl hydroperoxide

tert-Butyl hydroperoxide

tert-Butyl hydroperoxide price.
  • $30 - $6399.16
  • Product name: tert-Butyl hydroperoxide
  • CAS: 75-91-2
  • MF: C4H10O2
  • MW: 90.12
  • EINECS:200-915-7
  • MDL Number:MFCD00002130
  • Synonyms:1,1-dimethylethyl-hydroperoxid ;1,1-dimethylethylhydroperoxide ;trigonoxa-75(czech) ;trigonoxa-w70 ;USP -800;T-HYDRO(R);TERT-BUTYL HYDROPEROXIDE;tert-Butyl hydroperoxide(content≤80%,with di-tert-butyl hydroperoxide and/or type A thinner)tert-Butyl hydrogen peroxide
31 prices
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Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
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  • 250mg
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  • 5G
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  • 2500ml
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  • 18l
  • ManufacturerAlfa Aesar
  • Product numberA13926
  • Product descriptiontert-Butyl hydroperoxide 70% aq. soln.
  • Packaging100ml
  • Price$33.2
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13926
  • Product descriptiontert-Butyl hydroperoxide 70% aq. soln.
  • Packaging500ml
  • Price$67
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13926
  • Product descriptiontert-Butyl hydroperoxide 70% aq. soln.
  • Packaging2500ml
  • Price$281
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0032284
  • Product descriptionTERT-BUTYL HYDROPEROXIDE 95.00%
  • Packaging1L
  • Price$6399.16
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0032284
  • Product descriptionTERT-BUTYL HYDROPEROXIDE 95.00%
  • Packaging100ML
  • Price$2340.49
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0032284
  • Product descriptionTERT-BUTYL HYDROPEROXIDE 95.00%
  • Packaging25ML
  • Price$1066.64
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB161195
  • Product descriptiontert-Butyl hydroperoxide Solution 5.5 M in decane
  • Packaging5G
  • Price$50
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB31563
  • Product descriptionTert-Butyl hydroperoxide - 70% in water
  • Packaging25g
  • Price$50
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB31563
  • Product descriptionTert-Butyl hydroperoxide - 70% in water
  • Packaging50g
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB161195
  • Product descriptiontert-Butyl hydroperoxide Solution 5.5 M in decane
  • Packaging10g
  • Price$80
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB31563
  • Product descriptionTert-Butyl hydroperoxide - 70% in water
  • Packaging100g
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB161195
  • Product descriptiontert-Butyl hydroperoxide Solution 5.5 M in decane
  • Packaging25g
  • Price$125
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB31563
  • Product descriptionTert-Butyl hydroperoxide - 70% in water
  • Packaging250g
  • Price$150
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB31563
  • Product descriptionTert-Butyl hydroperoxide - 70% in water
  • Packaging500g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB161195
  • Product descriptiontert-Butyl hydroperoxide Solution 5.5 M in decane
  • Packaging50g
  • Price$215
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB161195
  • Product descriptiontert-Butyl hydroperoxide Solution 5.5 M in decane
  • Packaging100g
  • Price$375
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar A13926 tert-Butyl hydroperoxide 70% aq. soln. 100ml $33.2 2024-03-01 Buy
Alfa Aesar A13926 tert-Butyl hydroperoxide 70% aq. soln. 500ml $67 2024-03-01 Buy
Alfa Aesar A13926 tert-Butyl hydroperoxide 70% aq. soln. 2500ml $281 2024-03-01 Buy
American Custom Chemicals Corporation CHM0032284 TERT-BUTYL HYDROPEROXIDE 95.00% 1L $6399.16 2021-12-16 Buy
American Custom Chemicals Corporation CHM0032284 TERT-BUTYL HYDROPEROXIDE 95.00% 100ML $2340.49 2021-12-16 Buy
American Custom Chemicals Corporation CHM0032284 TERT-BUTYL HYDROPEROXIDE 95.00% 25ML $1066.64 2021-12-16 Buy
Biosynth Carbosynth FB161195 tert-Butyl hydroperoxide Solution 5.5 M in decane 5G $50 2021-12-16 Buy
Biosynth Carbosynth FB31563 Tert-Butyl hydroperoxide - 70% in water 25g $50 2021-12-16 Buy
Biosynth Carbosynth FB31563 Tert-Butyl hydroperoxide - 70% in water 50g $75 2021-12-16 Buy
Biosynth Carbosynth FB161195 tert-Butyl hydroperoxide Solution 5.5 M in decane 10g $80 2021-12-16 Buy
Biosynth Carbosynth FB31563 Tert-Butyl hydroperoxide - 70% in water 100g $100 2021-12-16 Buy
Biosynth Carbosynth FB161195 tert-Butyl hydroperoxide Solution 5.5 M in decane 25g $125 2021-12-16 Buy
Biosynth Carbosynth FB31563 Tert-Butyl hydroperoxide - 70% in water 250g $150 2021-12-16 Buy
Biosynth Carbosynth FB31563 Tert-Butyl hydroperoxide - 70% in water 500g $200 2021-12-16 Buy
Biosynth Carbosynth FB161195 tert-Butyl hydroperoxide Solution 5.5 M in decane 50g $215 2021-12-16 Buy
Biosynth Carbosynth FB161195 tert-Butyl hydroperoxide Solution 5.5 M in decane 100g $375 2021-12-16 Buy

Properties

Melting point :-2.8 °C
Boiling point :37 °C (15 mmHg)
Density :0.937 g/mL at 20 °C
vapor pressure :62 mmHg at 45 °C
refractive index :n20/D 1.403
Flash point :85 °F
storage temp. :2-8°C
pka :pK1: 12.80 (25°C)
form :Liquid
color :Clear colorless
Water Solubility :Miscible
Merck :14,1570
BRN :1098280
Exposure limits :No exposure limit is set. On the basis of its irritant properties a ceiling limit of 1.2 mg/m3 (0.3 ppm) is recommended.
Stability :Stable, but may explode if heated under confinement. Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants. Incompatible with reducing agents, combustible material, acids.
InChIKey :CIHOLLKRGTVIJN-UHFFFAOYSA-N
LogP :1.230 (est)
CAS DataBase Reference :75-91-2(CAS DataBase Reference)
NIST Chemistry Reference :Tert-butyl hydroperoxide(75-91-2)
EPA Substance Registry System :tert-Butyl hydroperoxide (75-91-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H242 Heating may cause a fire Self-reactive substances and mixtures; and Organic peroxides Type C, D,Type E, F
Type G
Danger
Warning
GHS hazard pictograms P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger GHS hazard pictograms P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P233 Keep container tightly closed.
P234 Keep only in original container.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see … on this label).
P331 Do NOT induce vomiting.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 Protect from sunlight.

Description

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

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