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ChemicalBook >> CAS DataBase List >> METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE price.
  • $45 - $349.6
  • Product name: METHYLMAGNESIUM IODIDE
  • CAS: 917-64-6
  • MF: CH3IMg
  • MW: 166.24
  • EINECS:213-031-1
  • MDL Number:MFCD00001026
  • Synonyms:METHYLMAGNESIUM IODIDE;MAGNESIUM METHYL IODIDE;iodomethyl-magnesiu ;methylmagnesiumiodidesol. ;Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L);iodomethylmagnesium;METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER;METHYLMAGNESIUM IODIDE, 3.0M SOLUTION IN DIETHYL ETHER
5 prices
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Brand
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 10ml
  • 100G
  • 100ml
  • 200ml
  • 800ml
  • ManufacturerSigma-Aldrich
  • Product number254363
  • Product descriptionMethylmagnesium iodide solution 3.0M in diethyl ether
  • Packaging800ml
  • Price$349.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number257109
  • Product descriptionMethylmagnesium iodide solution 3.0M in diethyl ether
  • Packaging200ml
  • Price$227
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number254363
  • Product descriptionMethylmagnesium iodide solution 3.0M in diethyl ether
  • Packaging100ml
  • Price$89.2
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberM0364
  • Product descriptionMethylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
  • Packaging100G
  • Price$62
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberM316653
  • Product descriptionMethylmagnesiumIodide(3.0MinDiethylether)
  • Packaging10ml
  • Price$45
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 254363 Methylmagnesium iodide solution 3.0M in diethyl ether 800ml $349.6 2024-03-01 Buy
Sigma-Aldrich 257109 Methylmagnesium iodide solution 3.0M in diethyl ether 200ml $227 2021-12-16 Buy
Sigma-Aldrich 254363 Methylmagnesium iodide solution 3.0M in diethyl ether 100ml $89.2 2024-03-01 Buy
TCI Chemical M0364 Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L) 100G $62 2024-03-01 Buy
TRC M316653 MethylmagnesiumIodide(3.0MinDiethylether) 10ml $45 2021-12-16 Buy

Properties

Density :1.26 g/mL at 20 °C
Flash point :-40 °C
BRN :1209226
InChIKey :AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System :Magnesium, iodomethyl- (917-64-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use … for extinction.
P422 Store contents under …

Description

Methylmagnesium iodide solution can be used:
  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

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