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ChemicalBook >> CAS DataBase List >> Diethyl azodicarboxylate

Diethyl azodicarboxylate

Diethyl azodicarboxylate price.
  • $15 - $2819.36
  • Product name: Diethyl azodicarboxylate
  • CAS: 1972-28-7
  • MF: C6H10N2O4
  • MW: 174.15
  • EINECS:217-821-7
  • MDL Number:MFCD00009103
  • Synonyms:Diazenedicarboxylic acid, diethyl ester;Diethyl (E)-1,2-diazenedicarboxylate;Diethyl diazodicarboxylate;dlethylazodicarboxylate ;Ethyl azodicarboxylate;Formic acid, azodi-, diethyl ester;DIETHYL AZODIFORMATE;Dimethyl azodicarboxyate
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  • Acrotein
  • Adipogen Life Sciences
  • AHH
  • Alfa Aesar
  • American Custom Chemicals Corporation
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  • Atlantic Research Chemicals
  • Biosynth Carbosynth
  • Matrix Scientific
  • Oakwood
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  • Usbiological
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  • 250mgs:
  • ManufacturerAcrotein
  • Product numberAS02042
  • Product descriptionDiethylazodicarboxylate 97%
  • Packaging250g
  • Price$106.33
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAS02042
  • Product descriptionDiethylazodicarboxylate 97%
  • Packaging100g
  • Price$48.95
  • Updated2021-12-16
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  • ManufacturerAdipogen Life Sciences
  • Product numberCDX-D0095-G010
  • Product descriptionDiethylazodicarboxylate ≥98%
  • Packaging10g
  • Price$35
  • Updated2021-12-16
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  • ManufacturerAdipogen Life Sciences
  • Product numberCDX-D0515-G100
  • Product descriptionDiethylazodicarboxylateSolution,40%intoluene
  • Packaging100g
  • Price$159
  • Updated2021-12-16
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  • ManufacturerAHH
  • Product numberMT-09100
  • Product descriptionDiethylazodicarboxylate 97%
  • Packaging500g
  • Price$380
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberL19348
  • Product descriptionDiethyl azodicarboxylate, 97%
  • Packaging5g
  • Price$33.3
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberL19348
  • Product descriptionDiethyl azodicarboxylate, 97%
  • Packaging25g
  • Price$92.6
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberL19348
  • Product descriptionDiethyl azodicarboxylate, 97%
  • Packaging100g
  • Price$274
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAPI0002335
  • Product descriptionDIETHYL AZODICARBOXYLATE 95.00%
  • Packaging100G
  • Price$2819.36
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR46008
  • Product descriptionDiethyldiazene-1,2-dicarboxylate,40%solutionintoluene
  • Packaging100g
  • Price$244
  • Updated2021-12-16
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  • ManufacturerAtlantic Research Chemicals
  • Product numberAN001154
  • Product description1,2-Diazenedicarboxylicacid,1,2-diethylester 95%
  • Packaging250mgs:
  • Price$17.67
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD01289
  • Product descriptionDiethyl azodicarboxylate
  • Packaging10g
  • Price$40
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD01289
  • Product descriptionDiethyl azodicarboxylate
  • Packaging25g
  • Price$80
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD01289
  • Product descriptionDiethyl azodicarboxylate
  • Packaging50g
  • Price$140
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD01289
  • Product descriptionDiethyl azodicarboxylate
  • Packaging100g
  • Price$235
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD01289
  • Product descriptionDiethyl azodicarboxylate
  • Packaging250g
  • Price$375
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AS02042 Diethylazodicarboxylate 97% 250g $106.33 2021-12-16 Buy
Acrotein AS02042 Diethylazodicarboxylate 97% 100g $48.95 2021-12-16 Buy
Adipogen Life Sciences CDX-D0095-G010 Diethylazodicarboxylate ≥98% 10g $35 2021-12-16 Buy
Adipogen Life Sciences CDX-D0515-G100 DiethylazodicarboxylateSolution,40%intoluene 100g $159 2021-12-16 Buy
AHH MT-09100 Diethylazodicarboxylate 97% 500g $380 2021-12-16 Buy
Alfa Aesar L19348 Diethyl azodicarboxylate, 97% 5g $33.3 2021-12-16 Buy
Alfa Aesar L19348 Diethyl azodicarboxylate, 97% 25g $92.6 2021-12-16 Buy
Alfa Aesar L19348 Diethyl azodicarboxylate, 97% 100g $274 2021-12-16 Buy
American Custom Chemicals Corporation API0002335 DIETHYL AZODICARBOXYLATE 95.00% 100G $2819.36 2021-12-16 Buy
Apolloscientific OR46008 Diethyldiazene-1,2-dicarboxylate,40%solutionintoluene 100g $244 2021-12-16 Buy
Atlantic Research Chemicals AN001154 1,2-Diazenedicarboxylicacid,1,2-diethylester 95% 250mgs: $17.67 2021-12-16 Buy
Biosynth Carbosynth FD01289 Diethyl azodicarboxylate 10g $40 2021-12-16 Buy
Biosynth Carbosynth FD01289 Diethyl azodicarboxylate 25g $80 2021-12-16 Buy
Biosynth Carbosynth FD01289 Diethyl azodicarboxylate 50g $140 2021-12-16 Buy
Biosynth Carbosynth FD01289 Diethyl azodicarboxylate 100g $235 2021-12-16 Buy
Biosynth Carbosynth FD01289 Diethyl azodicarboxylate 250g $375 2021-12-16 Buy

Properties

Melting point :6°C
Boiling point :106°C (13 mmHg)
Density :1.106
refractive index :n20/D 1.47
Flash point :85°C
storage temp. :2-8°C
solubility :Miscible with dichloromethane, diethyl ether and toluene.
form :liquid
color :Clear, orange
Sensitive :Air Sensitive
BRN :908662
Stability :Stable, but may explode if heated under confinement. May be shock sensitive. Decomposes vigorously if heated above 100 C. Incompatible with strong acids, strong bases, strong oxidizing agents, strong reducing agents. Light sensitive.
InChI :InChI=1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3
InChIKey :FAMRKDQNMBBFBR-FPLPWBNLSA-N
SMILES :N(C(OCC)=O)=NC(OCC)=O
CAS DataBase Reference :1972-28-7(CAS DataBase Reference)
NIST Chemistry Reference :Diethyl azo diformate(1972-28-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H242 Heating may cause a fire Self-reactive substances and mixtures; and Organic peroxides Type C, D,Type E, F
Type G
Danger
Warning
GHS hazard pictograms P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.

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