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ChemicalBook >> CAS DataBase List >> (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& price.
  • $65 - $2785
  • Product name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • CAS: 791616-62-1
  • MF: C36H17F12O4P
  • MW: 772.47
  • EINECS:
  • MDL Number:MFCD08689863
  • Synonyms:(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS;(R)-3,3μ-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1μ-bi-2-naphthol cyclic monophosphate, (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide;(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-;(11BR)-2,6-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-4-HYDROXY-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE);2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate
13 prices
Selected condition：
Brand
  • AK Scientific
  • Ambeed
  • Biosynth Carbosynth
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 25mg
  • 50mg
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • ManufacturerAK Scientific
  • Product number4711BB
  • Product description(S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging1g
  • Price$2785
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA313663
  • Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee
  • Packaging100mg
  • Price$78
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA313663
  • Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee
  • Packaging250mg
  • Price$158
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB103049
  • Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • Packaging25mg
  • Price$65
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB103049
  • Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • Packaging50mg
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB103049
  • Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • Packaging100mg
  • Price$170
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB103049
  • Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • Packaging250mg
  • Price$400
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB103049
  • Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • Packaging500mg
  • Price$750
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118696
  • Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
  • Packaging250mg
  • Price$713
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118696
  • Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
  • Packaging500mg
  • Price$1238
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118696
  • Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
  • Packaging1g
  • Price$2026
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number674605
  • Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%
  • Packaging100mg
  • Price$189
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1366
  • Product description(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
  • Packaging100mg
  • Price$127
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4711BB (S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 1g $2785 2021-12-16 Buy
Ambeed A313663 (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee 100mg $78 2021-12-16 Buy
Ambeed A313663 (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee 250mg $158 2021-12-16 Buy
Biosynth Carbosynth FB103049 (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide 25mg $65 2021-12-16 Buy
Biosynth Carbosynth FB103049 (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide 50mg $100 2021-12-16 Buy
Biosynth Carbosynth FB103049 (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide 100mg $170 2021-12-16 Buy
Biosynth Carbosynth FB103049 (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide 250mg $400 2021-12-16 Buy
Biosynth Carbosynth FB103049 (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide 500mg $750 2021-12-16 Buy
Matrix Scientific 118696 (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0% 250mg $713 2021-12-16 Buy
Matrix Scientific 118696 (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0% 500mg $1238 2021-12-16 Buy
Matrix Scientific 118696 (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0% 1g $2026 2021-12-16 Buy
Sigma-Aldrich 674605 (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95% 100mg $189 2024-03-01 Buy
Strem Chemicals 15-1366 (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee) 100mg $127 2024-03-01 Buy

Properties

Melting point :162-175 °C
Boiling point :722.1±70.0 °C(Predicted)
Density :1.63±0.1 g/cm3(Predicted)
storage temp. :2-8°C
form :Powder
pka :1.09±0.20(Predicted)
color :white to light-yellow
optical activity :[α]20/D -220°, c = 1 in chloroform (typical)
InChIKey :DQORDVSQWPKAQJ-UHFFFAOYSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

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