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ChemicalBook >> CAS DataBase List >> Lithium triisobutylhydroborate

Lithium triisobutylhydroborate

Lithium triisobutylhydroborate price.
  • $77 - $2090
  • Product name: Lithium triisobutylhydroborate
  • CAS: 38721-52-7
  • MF: C12H28B.Li
  • MW: 190.1
  • EINECS:254-101-1
  • MDL Number:MFCD00011708
  • Synonyms:LITHIUM TRI-S-BUTYLHYDROBORATE;LITHIUM TRI-SEC-BUTYLHYDRIDOBORATE;LITHIUM TRIISOBUTYLHYDROBORATE;L-SELECTRIDE(R);l-selectride solution;(beta-4)-borate(1-hydrotris(1-methylpropyl)-lithium;LITHIUM TRI-SEC-BUTYLBOROHYDRIDE, 1M IN THF;Lithium tri-sec-butylborohydride1M solution in THFAcroSeal§3
10 prices
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Brand
  • Alfa Aesar
  • Chemenu
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 100g
  • 100ml
  • 500g
  • 500ml
  • 800ml
  • 1000g
  • 8l
  • ManufacturerAlfa Aesar
  • Product number043034
  • Product descriptionLithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$82
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043845
  • Product descriptionLithium tri-sec-butylborohydride 1.0M in THF
  • Packaging500ml
  • Price$266
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043034
  • Product descriptionLithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$332
  • Updated2024-03-01
  • Buy
  • ManufacturerChemenu
  • Product numberCM328863
  • Product descriptionLithiumtriisobutylhydroborate 95%+
  • Packaging1000g
  • Price$605
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number178497
  • Product descriptionL-Selectride? solution 1.0M in THF
  • Packaging8l
  • Price$2090
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number178497
  • Product descriptionL-Selectride? solution 1.0M in THF
  • Packaging800ml
  • Price$451
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number178497
  • Product descriptionL-Selectride? solution 1.0M in THF
  • Packaging100ml
  • Price$86.6
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-1400
  • Product descriptionLithium triisobutylhydroborate
  • Packaging500g
  • Price$308
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-1400
  • Product descriptionLithium triisobutylhydroborate
  • Packaging100g
  • Price$77
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberS253005
  • Product descriptionL-SelectrideSolution(1.0?MinTHF)
  • Packaging100mL
  • Price$330
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 043034 Lithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles 100ml $82 2024-03-01 Buy
Alfa Aesar 043845 Lithium tri-sec-butylborohydride 1.0M in THF 500ml $266 2021-12-16 Buy
Alfa Aesar 043034 Lithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles 500ml $332 2024-03-01 Buy
Chemenu CM328863 Lithiumtriisobutylhydroborate 95%+ 1000g $605 2021-12-16 Buy
Sigma-Aldrich 178497 L-Selectride? solution 1.0M in THF 8l $2090 2024-03-01 Buy
Sigma-Aldrich 178497 L-Selectride? solution 1.0M in THF 800ml $451 2024-03-01 Buy
Sigma-Aldrich 178497 L-Selectride? solution 1.0M in THF 100ml $86.6 2024-03-01 Buy
Strem Chemicals 03-1400 Lithium triisobutylhydroborate 500g $308 2024-03-01 Buy
Strem Chemicals 03-1400 Lithium triisobutylhydroborate 100g $77 2024-03-01 Buy
TRC S253005 L-SelectrideSolution(1.0?MinTHF) 100mL $330 2021-12-16 Buy

Properties

Density :0.89 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
solubility :Miscible with tetrahydrofuran.
form :Liquid
color :Colorless to yellow
Water Solubility :reacts
Sensitive :Moisture Sensitive
BRN :4007327
InChIKey :ACJKNTZKEFMEAK-UHFFFAOYSA-N
CAS DataBase Reference :38721-52-7(CAS DataBase Reference)
EPA Substance Registry System :Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)- (38721-52-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P422 Store contents under …

Description

It finds its application as a selective reducing agent. It is also employed as a reagent for enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters, diastereoselective reduction reactions, hydride reduction of the Danishefsky pyranones, asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes and in the synthesis of alkanols by carbonylation reactions.

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