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ChemicalBook >> CAS DataBase List >> (S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide price.
  • $4 - $1588.13
  • Product name: (S)-(-)-2-Methyl-2-propanesulfinamide
  • CAS: 343338-28-3
  • MF: C4H11NOS
  • MW: 121.2
  • EINECS:640-158-3
  • MDL Number:MFCD05861480
  • Synonyms:2-METHYL-2-PROPANE-SULFINAMIDE(S-ISOMER);(S)-tert-Butylsulfinamide, (>98.0% ee), 97+%;(S)-(-)-2-METHYL-2-PROPANESULPHINAMIDE;(S)-(-)-2-METHYL-PROPANE-2-SULFINIC ACID AMIDE;(S)-(-)-TERT-BUTYLSULFINAMIDE;(S)-(-)-TERT-BUTYL SULPHINAMIDE;(S)-(-)-T-BUTYLMETHYLSULFINAMIDE;(S)-(-)-2-Methylpropane-2-sulphinamide 98%
52 prices
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Brand
  • Acrotein
  • AHH
  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • BroadPharm
  • Chem-Impex
  • ChemPep
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Frontier Specialty Chemicals
  • JR MediChem
  • Matrix Scientific
  • Oakwood
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  • TCI Chemical
  • TRC
Package
  • 1g
  • 5g
  • 10g
  • 25g
  • 100g
  • 250G
  • 500g
  • 1KG
  • ManufacturerAcrotein
  • Product numberAM-3360
  • Product description(S)-tert-Butylsulfinamide 97%
  • Packaging25g
  • Price$59.58
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-18727
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide 98%
  • Packaging25g
  • Price$720
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ80007
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide
  • Packaging1g
  • Price$17
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27115
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide, 97%
  • Packaging1g
  • Price$76.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27115
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide, 97%
  • Packaging5g
  • Price$261
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27115
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide, 97%
  • Packaging25g
  • Price$953
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA114422
  • Product description(S)-2-Methylpropane-2-sulfinamide 98%
  • Packaging5g
  • Price$7
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA114422
  • Product description(S)-2-Methylpropane-2-sulfinamide 98%
  • Packaging10g
  • Price$13
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA114422
  • Product description(S)-2-Methylpropane-2-sulfinamide 98%
  • Packaging25g
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA114422
  • Product description(S)-2-Methylpropane-2-sulfinamide 98%
  • Packaging100g
  • Price$86
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA114422
  • Product description(S)-2-Methylpropane-2-sulfinamide 98%
  • Packaging500g
  • Price$423
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0001553
  • Product description(S)-(-)-TERT-BUTYLSULFINAMIDE 95.00%
  • Packaging1G
  • Price$627.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0001553
  • Product description(S)-(-)-TERT-BUTYLSULFINAMIDE 95.00%
  • Packaging5G
  • Price$888.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0001553
  • Product description(S)-(-)-TERT-BUTYLSULFINAMIDE 95.00%
  • Packaging25G
  • Price$1588.13
  • Updated2021-12-16
  • Buy
  • ManufacturerBroadPharm
  • Product numberBP-20535
  • Product description(S)-(-)2-methyl-2-propanesulfinamide
  • Packaging5G
  • Price$58
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31474
  • Product description(S)-(-)-2-Methyl-2-propanesulfinamide,≥99%(HPLC,Chiralpurity) ≥99%(HPLC,Chiralpurity)
  • Packaging1KG
  • Price$827.01
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AM-3360 (S)-tert-Butylsulfinamide 97% 25g $59.58 2021-12-16 Buy
AHH MT-18727 (S)-(-)-2-Methyl-2-propanesulfinamide 98% 25g $720 2021-12-16 Buy
AK Scientific J80007 (S)-(-)-2-Methyl-2-propanesulfinamide 1g $17 2021-12-16 Buy
Alfa Aesar H27115 (S)-(-)-2-Methyl-2-propanesulfinamide, 97% 1g $76.65 2024-03-01 Buy
Alfa Aesar H27115 (S)-(-)-2-Methyl-2-propanesulfinamide, 97% 5g $261 2024-03-01 Buy
Alfa Aesar H27115 (S)-(-)-2-Methyl-2-propanesulfinamide, 97% 25g $953 2024-03-01 Buy
Ambeed A114422 (S)-2-Methylpropane-2-sulfinamide 98% 5g $7 2021-12-16 Buy
Ambeed A114422 (S)-2-Methylpropane-2-sulfinamide 98% 10g $13 2021-12-16 Buy
Ambeed A114422 (S)-2-Methylpropane-2-sulfinamide 98% 25g $28 2021-12-16 Buy
Ambeed A114422 (S)-2-Methylpropane-2-sulfinamide 98% 100g $86 2021-12-16 Buy
Ambeed A114422 (S)-2-Methylpropane-2-sulfinamide 98% 500g $423 2021-12-16 Buy
American Custom Chemicals Corporation CCH0001553 (S)-(-)-TERT-BUTYLSULFINAMIDE 95.00% 1G $627.17 2021-12-16 Buy
American Custom Chemicals Corporation CCH0001553 (S)-(-)-TERT-BUTYLSULFINAMIDE 95.00% 5G $888.2 2021-12-16 Buy
American Custom Chemicals Corporation CCH0001553 (S)-(-)-TERT-BUTYLSULFINAMIDE 95.00% 25G $1588.13 2021-12-16 Buy
BroadPharm BP-20535 (S)-(-)2-methyl-2-propanesulfinamide 5G $58 2021-12-16 Buy
Chem-Impex 31474 (S)-(-)-2-Methyl-2-propanesulfinamide,≥99%(HPLC,Chiralpurity) ≥99%(HPLC,Chiralpurity) 1KG $827.01 2021-12-16 Buy

Properties

Melting point :97-101 °C(lit.)
alpha :-4.5 º (c=1, CHCl3)
Boiling point :220.0±23.0 °C(Predicted)
Density :1.124
storage temp. :2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
pka :10.11±0.50(Predicted)
form :Crystalline Powder
color :White
optical activity :[α]20/D 4.5°, c = 1 in chloroform
Stability :store cold
InChI :InChI=1/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/s3
InChIKey :CESUXLKAADQNTB-SSDOTTSWSA-N
SMILES :CC(C)([S@@](N)=O)C |&1:3,r|
CAS DataBase Reference :343338-28-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

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