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ChemicalBook >> CAS DataBase List >> 3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE price.
  • $14 - $550.65
  • Product name: 3-BROMOCYCLOHEXENE
  • CAS: 1521-51-3
  • MF: C6H9Br
  • MW: 161.04
  • EINECS:
  • MDL Number:MFCD00013775
  • Synonyms:1-Bromo-2-cyclohexene;2-Cyclohexenyl bromide;3-Bromo-1-cyclohexene;1,2,3,4-TETRAHYDROBROMOBENZENE;2-CYCLOHEXEN-1-YL BROMIDE;(+/-)-3-BROMOCYCLOHEXENE;3-BROMOCYCLOHEXENE;TIMTEC-BB SBB007864
15 prices
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Brand
  • AK Scientific
  • Alfa Aesar
  • Matrix Scientific
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 1g
  • 5mL
  • 5g
  • 10ml
  • 25g
  • 25mL
  • 50ml
  • 100g
  • 250ml
  • ManufacturerAK Scientific
  • Product numberR943
  • Product description3-Bromocyclohexene
  • Packaging1g
  • Price$69
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA10370
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging5g
  • Price$40.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA10370
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging25g
  • Price$173.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA10370
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging100g
  • Price$550.65
  • Updated2024-03-01
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene 95+%
  • Packaging5g
  • Price$35
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090492
  • Product description3-Bromocyclohex-1-ene 95+%
  • Packaging100g
  • Price$449
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging1g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging5g
  • Price$39
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number091672
  • Product description3-Bromocyclohex-1-ene
  • Packaging25g
  • Price$160
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging10ml
  • Price$99.5
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging50ml
  • Price$261
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging250ml
  • Price$545.4
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberB0943
  • Product description3-Bromocyclohexene >90.0%(GC)
  • Packaging5mL
  • Price$107
  • Updated2024-03-01
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  • ManufacturerTCI Chemical
  • Product numberB0943
  • Product description3-Bromocyclohexene >90.0%(GC)
  • Packaging25mL
  • Price$532
  • Updated2024-03-01
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  • ManufacturerTRC
  • Product numberB679088
  • Product description3-Bromocyclohexene
  • Packaging1g
  • Price$130
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific R943 3-Bromocyclohexene 1g $69 2021-12-16 Buy
Alfa Aesar A10370 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 5g $40.65 2024-03-01 Buy
Alfa Aesar A10370 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 25g $173.65 2024-03-01 Buy
Alfa Aesar A10370 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 100g $550.65 2024-03-01 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 95+% 5g $35 2021-12-16 Buy
Matrix Scientific 090492 3-Bromocyclohex-1-ene 95+% 100g $449 2021-12-16 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 1g $14 2021-12-16 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 5g $39 2021-12-16 Buy
Oakwood 091672 3-Bromocyclohex-1-ene 25g $160 2021-12-16 Buy
Sigma-Aldrich 333549 3-Bromocyclohexene technical grade, 90% 10ml $99.5 2024-03-01 Buy
Sigma-Aldrich 333549 3-Bromocyclohexene technical grade, 90% 50ml $261 2024-03-01 Buy
Sigma-Aldrich 333549 3-Bromocyclohexene technical grade, 90% 250ml $545.4 2024-03-01 Buy
TCI Chemical B0943 3-Bromocyclohexene >90.0%(GC) 5mL $107 2024-03-01 Buy
TCI Chemical B0943 3-Bromocyclohexene >90.0%(GC) 25mL $532 2024-03-01 Buy
TRC B679088 3-Bromocyclohexene 1g $130 2021-12-16 Buy

Properties

Melting point :131-134 °C
Boiling point :57-58 °C/12 mmHg (lit.)
Density :1.4 g/mL at 25 °C (lit.)
refractive index :n20/D 1.528(lit.)
Flash point :130 °F
storage temp. :-20°C
form :Solid
color :White to off-white
Water Solubility :Not miscible or difficult to mix in water.
BRN :635953
InChIKey :AJKDUJRRWLQXHM-UHFFFAOYSA-N
CAS DataBase Reference :1521-51-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger. It is also used in the synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine.1 It was also used in the synthesis of enantiopure cyclohexitols such as muco-quercitol, D-chiro-inocitol and allo-inocitol.

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