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4-???-2,1,3-???????

4-???-2,1,3-???????
4-???-2,1,3-??????? ??? ???
?? ??:
22034-13-5
???:
4-???-2,1,3-???????
???(??):
4-???-2,1,3-???????
???:
4-bromo-2,1,3-benzothiadiazole
???(??):
BT-BR;AKOS BBS-00002903;IFLAB-BB F1918-0061;4-BROMO-2,1,3-BENZOTHIAZOLE;4-bromo-2,1,3-benzothiadiazoL;4-BROMO-2,1,3-BENZOTHIADIAZOLE;4-Bromobenzo[2,1,3]thiadiazole;4-Bromo-benzo[1,2,5]thiadiazole;2,1,3-Benzothiadiazole, 4-bromo-;4-BroMobenzo[c][1,2,5]thiadiazole
CBNumber:
CB8376884
???:
C6H3BrN2S
??? ??:
215.07
MOL ??:
22034-13-5.mol
MSDS ??:
SDS

4-???-2,1,3-??????? ??

???
80 °C
?? ?
272.2±13.0 °C(Predicted)
??
1.859±0.06 g/cm3(Predicted)
?? ??
2-8°C
?? ?? (pKa)
-1.02±0.45(Predicted)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi,Xn
?? ???? ?? 22
HS ?? 2934999090
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H332 ???? ??? ?? ?? ?? ?? ?? 4 ?? GHS hazard pictograms P261, P271, P304+P340, P312
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P310 ?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.

4-???-2,1,3-??????? C??? ??, ??, ??

??

The Sonogashira cross-coupling reaction between 4-bromo-2, 1,3-benzothiadiazole, and the respective para-substituted phenylethynyl derivatives could synthesize the BTDs. In addition, the BTD-Ph is prepared by reacting 4-bromo-2,1,3-benzothiadiazole (Br-BTD)and palladium-MAI catalyst, and the dynamic phenylboronic acid reagent in the starting system or dynamic o-amino pyridine reagent[1-2].

4-???-2,1,3-??????? ?? ?? ? ???

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4-???-2,1,3-??????? ?? ??

???( 131)?? ??
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