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ChemicalBook >> CAS DataBase List >>Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride

CAS No.
14264-16-5
Chemical Name:
Bis(triphenylphosphine)nickel(II)chloride
Synonyms
NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;phosphine)nickeL;Bis(triphenylphosphine)nick
CBNumber:
CB8433158
Molecular Formula:
C36H30Cl2NiP2
Molecular Weight:
654.17
MDL Number:
MFCD00009592
MOL File:
14264-16-5.mol
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

Bis(triphenylphosphine)nickel(II)chloride Properties

Melting point 250 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Crystals or Powder
color Dark green to dark gray
Water Solubility insoluble
Sensitive Hygroscopic
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference 14264-16-5(CAS DataBase Reference)
EWG's Food Scores 1
NIST Chemistry Reference dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H350-H412
Precautionary statements  P201-P273-P280-P302+P352-P308+P313
Hazard Codes  T
Risk Statements  45-43-52/53-34-20/21/22
Safety Statements  53-36/37-45-60-36/37/39-26
RIDADR  3260
WGK Germany  3
RTECS  QR6170000
21
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29310095
NFPA 704
0
3 0

Bis(triphenylphosphine)nickel(II)chloride price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 10g $56.8 2024-03-01 Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 50g $106.8 2024-03-01 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 10g $43 2024-03-01 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 100g $200 2024-03-01 Buy
Alfa Aesar 013930 Dichlorobis(triphenylphosphine)nickel(II), 98% 14264-16-5 10g $43.65 2024-03-01 Buy
Product number Packaging Price Buy
237116 10g $56.8 Buy
237116 50g $106.8 Buy
B1571 10g $43 Buy
B1571 100g $200 Buy
013930 10g $43.65 Buy

Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Uses,Production

Reaction

  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Reactions of 14264-16-5

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Uses

suzuki reaction

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Global( 373)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8810 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12835 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18751 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
AB PharmaTech,LLC
323-480-4688 sales@acrospharmatech.com United States 989 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Wuhan Pengo Technology.,Ltd.
+86-27-81330736 +86-13628634921 sunny.w@boronicgroup.com CHINA 171 58

View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(triphenylphosphine)nickel(II)chloride pictures 2024-12-04 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $10.00 / KG 1KG 99% 5tons Hebei Weibang Biotechnology Co., Ltd
Bis(triphenylphosphine)nickel(II)chloride pictures 2023-08-23 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Bis(triphenylphosphine)nickel(II)chloride pictures 2023-04-17 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $200.00 / KG 1KG 99% 500t Shanghai Yunao International Trade Co., Ltd
Dichlorobis(triphenyIphosphine)-nickel tributyl-phosphin compd. with nickelchloride Nickel(II) chloride bis(triphenylphosphine) Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride Phosphine, tributyl-, compound with nickel chloride (2:1) Dichlorobis(triphenylphosphine)nickel(Ⅱ) Dichlorobis(triphenylphosphine)nickel(II), 98+% Dichlorobis(triphehylphosphine)nickel(II) ,98% Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2 NSC 137147 BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI Bis (triphenylphosphine) nickel chloride Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis Bis(triphenylphosphine)nickel(II) dichloride synthesis grade Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2 NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE Bis(tri-N-butylphosphine)dichloronickel bis(triphenylphosphine)dichloro-nicke Bis(triphenylphosphine)dichloronickel Dichlorobis(triphenyIphosphine)-nickel(II) dichlorobis(triphenylphosphine)-nicke Nickel, bis(triphenylphosphine)dichloro- Nickel, dichlorobis(triphenylphosphine)- Phosphine, tributyl-, compd. with nickelchloride (2:1) bis(triphenylphosphine)nickle(II) Bis-(triphenylphosphino)-nickel chloride tributyl-phosphincompd.withnickelchloride(2:1) Bis(triphenylphosphine)nickel(II) chloride for synthesis TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE Bis(triphenylphosphine)nickel(II) chloride, 98+% Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II) Bis(triphenylphosphine)nickel(II)chloride,99% Dichloro bis (Triphenyl phosphine) Nickel catalyst Bis(triphenylphosphine)nick Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2 Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis Bis(triphenylphosphine)nickel(II) Dichloride > (II) dichL phosphine)nickeL Bis(triphenylphosphine)nickel(II)chloride ISO 9001:2015 REACH NiCl2(PPh3)2 DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE Bis(triphenylphosphine)nickel dichloride Bis(triphenylphosphin)nickel(II)chlorid dichloronickel triphenylphosphane is(triphenylphosphine)nickel(II)chloride (PPh3)2NiCl2 NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE Bis(Triphenylphosphoranyl)nickel(iv) chloride 14264-16-5 14262-16-5