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ChemicalBook >> CAS DataBase List >>Bismuth(III) Oxide

Bismuth(III) Oxide

CAS No.
1304-76-3
Chemical Name:
Bismuth(III) Oxide
Synonyms
BISMUTH OXIDE;BISMUTH(III) OXIDE;Dibismuth trioxide;Bismuth(III) oxide,99.9%;Bi2-O3;Bismite;c.i.77160;C.I. 77160;bismuthyellow;Bismuth 0xide
CBNumber:
CB5716407
Molecular Formula:
BiO3-
Molecular Weight:
256.98
MDL Number:
MFCD00003462
MOL File:
1304-76-3.mol
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

Bismuth(III) Oxide Properties

Melting point 825 °C
Boiling point 1890°C
Density 8.9
Flash point 1890°C
storage temp. Store at +5°C to +30°C.
solubility 0.006g/l practically insoluble
form powder
color Yellow
Specific Gravity 8.9
Odor Odorless
Water Solubility INSOLUBLE
Merck 14,1273
crystal system Monoclinic
Space group P21/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.58480.81660.75190113900.3301
Stability Stable.
InChIKey KOCGCHBRHPOCBW-UHFFFAOYSA-N
CAS DataBase Reference 1304-76-3(CAS DataBase Reference)
FDA UNII A6I4E79QF1
NIST Chemistry Reference bismuth(III) oxide(1304-76-3)
EPA Substance Registry System Bismuth trioxide (1304-76-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H303
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  26-36/37-36
WGK Germany  2
RTECS  EB2984460
TSCA  Yes
HS Code  2825 90 85
Toxicity LD50 orally in Rabbit: 5000 mg/kg
NFPA 704
0
0 0

Bismuth(III) Oxide price More Price(63)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 202827 Bismuth(III) oxide powder, 99.999% trace metals basis 1304-76-3 10g $60.7 2024-03-01 Buy
Sigma-Aldrich 202827 Bismuth(III) oxide powder, 99.999% trace metals basis 1304-76-3 50g $188 2024-03-01 Buy
Sigma-Aldrich 1.01862 Bismuth(III) oxide EMPLURA? 1304-76-3 1kg $839 2024-03-01 Buy
Sigma-Aldrich 1.01862 Bismuth(III) oxide EMPLURA? 1304-76-3 25kg $12140 2024-03-01 Buy
Alfa Aesar 010658 Bismuth(III) oxide, Puratronic?, 99.9995% (metals basis) 1304-76-3 50g $110 2024-03-01 Buy
Product number Packaging Price Buy
202827 10g $60.7 Buy
202827 50g $188 Buy
1.01862 1kg $839 Buy
1.01862 25kg $12140 Buy
010658 50g $110 Buy

Bismuth(III) Oxide Chemical Properties,Uses,Production

Chemical Properties

Bismuth(III) oxide is the compound produced by heating the metal, or its carbonate, in air. It is definitely a basic oxide, dissolving readily in acid solutions, and unlike the arsenic or antimony compounds, not amphiprotic in solution, although it forms stoichiometric addition compounds on heating with oxides of a number of other metals. It exists in three modifications, white rhombohedral, yellow rhombohedral, and gray-black cubical. Bismuth(II) oxide, BiO, has been produced by heating the basic oxalate.

Chemical Properties

Heavy, Yellow Powder

Physical properties

Yellow monoclinic crystal or powder; density 8.90 g/cm3; melts at 817°C; vaporizes at 1,890°C; insoluble in water; soluble in acids.

Occurrence

Bismuth trioxide occurs in nature as mineral bismite. The oxide is used in fireproofing of papers and polymers; in enameling cast iron ceramic; and in disinfectants.

Uses

In disinfectants, magnets, glass, rubber vulcanization; in fireproofing of papers and polymers; in catalysts.

Uses

Bismuth(III) oxide is used in the preparation of BiFeO3perovskite nanoparticles. It finds use in disinfectants, magnets, glass, rubber, vulcanization, fireproofing papers and polymers and catalysts. Bismuth trioxide brings about the "dragon's eggs" effect in fireworks, as a replacement of red lead. Bismuth(III) compounds are attractive reagents and catalysts in organic synthesis because of their low cost and ease of handling. Bismuth trioxide nanoparticles also play an important role in high energy gas generators. The alpha crystalline form of bismuth(III) oxide has p-type electronic conductivity.

Preparation

Bismuth trioxide is commercially made from bismuth subnitrate. The latter is produced by dissolving bismuth in hot nitric acid. Addition of excess sodium hydroxide followed by continuous heating of the mixture precipitates bismuth trioxide as a heavy yellow powder. Also, the trioxide can be prepared by ignition of bismuth hydroxide.

General Description

Bismuth (III) oxide is a yellow, monoclinic crystalline powder. It is insoluble in water and hydroxide solutions but dissolves in acids to form bismuth (III) salts. It can be prepared by heating bismuth in air or by heating hydroxides, carbonates or nitrates of bismuth.

Structure and conformation

Bismuth(III) Oxides are the deeply studied class of bismuth compounds, and they present four different phases. At room temperature, monoclinic α-Bi2O3 is the common stable phase with a polymeric-distorted layered structure composed of pentacoordinate bismuth atoms enclosed into pseudo-octahedral units. At a temperature higher than 710 °C, the α phase is converted into the cubic δ phase, which has a defective structure with random oxygen vacancies. The β phase and several oxygen-rich forms are closely related to the δ phase. In particular, the vacancy structures of highly defected bismuth oxides are some sites filled with O?2 and Bi(III) and Bi (V) sites. Bismuth oxide γ-phase also shows a cubic structure, but it is highly unstable and hard to synthesize without supporting it onto other oxides or metallic species. The other two polymorphic metastable bismuth oxide phases are known as the ω phase, stable at temperatures higher than 800 °C and the ε phase, isolated in 2006 by Cornei and co-workers[1]. Bismuth trioxide

References

[1] Mattia Bartoli, Alberto Tagliaferro, Pravin Jagdale. “A Short Review on Biomedical Applications of Nanostructured Bismuth Oxide and Related Nanomaterials.” Materials 13 22 (2020).

Bismuth(III) Oxide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 516)Suppliers
Supplier Tel Email Country ProdList Advantage
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View Lastest Price from Bismuth(III) Oxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bismuth trioxide pictures 2024-12-13 Bismuth trioxide
1304-76-3
US $0.00-0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Bismuth trioxide pictures 2024-12-12 Bismuth trioxide
1304-76-3
US $11748.00-11740.00 / Tons 1Tons 99.99% 100Tons Hebei Dangtong Import and export Co LTD
Bismuth trioxide pictures 2024-12-03 Bismuth trioxide
1304-76-3
US $9.90 / KG 1KG 99% 5tons Hebei Weibang Biotechnology Co., Ltd
  • Bismuth trioxide pictures
  • Bismuth trioxide
    1304-76-3
  • US $0.00-0.00 / KG
  • 98%min
  • WUHAN FORTUNA CHEMICAL CO., LTD
  • Bismuth trioxide pictures
  • Bismuth trioxide
    1304-76-3
  • US $11748.00-11740.00 / Tons
  • 99.99%
  • Hebei Dangtong Import and export Co LTD
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