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ChemicalBook >> CAS DataBase List >>Methyl anisate

Methyl anisate

CAS No.
121-98-2
Chemical Name:
Methyl anisate
Synonyms
FEMA 2679;METHYL ANISATE;Methyl-p-anisat;METHYL P-ANISATE;METHYL 4-ANISATE;Methyl anisate,99%;PARA-METHYLANISATE;Methylp-Anisate>RARECHEM AL BF 0083;METHYL PARA-ANISATE
CBNumber:
CB5189041
Molecular Formula:
C9H10O3
Molecular Weight:
166.17
MDL Number:
MFCD00008437
MOL File:
121-98-2.mol
MSDS File:
SDS
Last updated:2024-10-30 18:52:02

Methyl anisate Properties

Melting point 47-51 °C (lit.)
Boiling point 244-245 °C (lit.)
Density 1.1708 (rough estimate)
refractive index 1.5224 (estimate)
FEMA 2679 | METHYL ANISATE
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Methanol (Slightly)
form Solid
color Plates from alcohol. Flakes from EtOH or Et2O
Odor at 100.00 %. herbal anise sweet
Odor Type anisic
Water Solubility 643.1mg/L(20 ºC)
JECFA Number 884
BRN 2208571
Dielectric constant 4.3（33℃）
LogP 2.27
CAS DataBase Reference 121-98-2(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) METHYL ANISATE
FDA 21 CFR 172.515
EWG's Food Scores 1
FDA UNII 2MFL7873W9
NIST Chemistry Reference Benzoic acid, 4-methoxy-, methyl ester(121-98-2)
EPA Substance Registry System Benzoic acid, 4-methoxy-, methyl ester (121-98-2)

SAFETY

Risk and Safety Statements

Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  2
RTECS  BZ4925000
TSCA  Yes
HS Code  29189900
Toxicity LD50 orl-rat: >5 g/kg FCTXAV 14,481,76
NFPA 704
1
2 0

Methyl anisate price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W267902 Methyl p-anisate ≥99%, FG 121-98-2 1kg $224 2024-03-01 Buy
Sigma-Aldrich W267902 Methyl p-anisate ≥99%, FG 121-98-2 5kg $1080 2024-03-01 Buy
Sigma-Aldrich 253146 Methyl p-anisate 99% 121-98-2 100g $31.86 2024-03-01 Buy
Sigma-Aldrich 253146 Methyl p-anisate 99% 121-98-2 25g $39.5 2024-03-01 Buy
Sigma-Aldrich W267902 Methyl p-anisate ≥99%, FG 121-98-2 250g $119 2023-06-20 Buy
Product number Packaging Price Buy
W267902 1kg $224 Buy
W267902 5kg $1080 Buy
253146 100g $31.86 Buy
253146 25g $39.5 Buy
W267902 250g $119 Buy

Methyl anisate Chemical Properties,Uses,Production

Description

Methyl anisate is the methyl ester of p-anisic acid.

Chemical Properties

white crystalline mass

Chemical Properties

Methyl anisate has an herbaceous, anise-like odor and a sweet taste similar to melon.

Chemical Properties

Methyl anisate has a herbaceous, anise-like odor and a sweet taste similar to melon.

Occurrence

Reported found in the mushroom variety Trametes graveolens, feyoa fruit and peel (Feijoa sellowiana), white wine, cocoa, tea, guava, starfruit, Bourbon vanilla, Tahiti vanilla, mountain papaya, sapodilla fruit and Illicium verum.

Uses

Methyl p-anisate has been used as a standard for the quantification of odorant compounds in French mimosa absolute oil by GC-Sniffing.

Definition

ChEBI: A benzoate ester obtained by the formal condensation of the carboy group of 4-methoxybenzoic acid with methanol.

Preparation

By esterification of anisic acid with methanol or from sodium anisate, dimethyl sulfate and small amounts of methanol.

Aroma threshold values

Aroma characteristics at 10.0%: sweet, creamy, anisic vanillalike, slightly spicy, woody and powdery heliotropine-like.

Taste threshold values

Taste characteristics at 10 ppm: spicy, sweet, anisic-like with a woody vanilla, licorice and methyl salicylate nuances and with a lingering sweet coumarin vanilla aftertaste.

Synthesis Reference(s)

Tetrahedron Letters, 33, p. 1959, 1992 DOI: 10.1016/0040-4039(92)88113-J

General Description

Methyl p-anisate is a volatile compound released from Mycobacterium tuberculosis and is detected in the breath of tuberculosis patients. It is a potential biomarker for mycobacteria.

Biochem/physiol Actions

Taste at 10 ppm

Safety Profile

Low toxicity by ingestion and skincontact. A skin irritant. When heated todecomposition it emits acrid smoke and irritating fumes.

Solubility in organics

Soluble in alcohol and oils. Poorly soluble in Propylene glycol.

Purification Methods

Distil the ester and/or crystallise it from EtOH. [Beilstein 10 H 159, 10 III 297, 10 IV 360.]

123-11-5
74-88-4
121-98-2
Synthesis of Methyl anisate from p-Anisaldehyde and Iodomethane
Global( 340)Suppliers
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View Lastest Price from Methyl anisate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl anisate pictures 2024-10-30 Methyl anisate
121-98-2
 US $31.00 / g 10g TargetMol Chemicals Inc.
Methyl anisate pictures 2024-05-11 Methyl anisate
121-98-2
 US $0.00-0.00 / kg 1kg 99% 500000kg Hebei Kingfiner Technology Development Co.Ltd
Methyl anisate pictures 2023-02-13 Methyl anisate
121-98-2
 US $80.00 / kg 1kg 99% 100MT Hebei baicao biology science and technology co., ltd
  • Methyl anisate pictures
  • Methyl anisate
    121-98-2
  • US $0.00-0.00 / kg
  • 99%
  • Hebei Kingfiner Technology Development Co.Ltd
  • Methyl anisate pictures
  • Methyl anisate
    121-98-2
  • US $80.00 / kg
  • 99%
  • Hebei baicao biology science and technology co., ltd
P-ANISIC ACID METHYL ESTER RARECHEM AL BF 0083 METHYLPARA-METHOXYBENZOATE Methyl-p-anisat Methyl 4-methoxybenzoate, 98+% METHYL ANISATE, NATURAL Methyl anisate,99% P-Methoxy-Benzoicacimethylest p-Anisic acid methyl ester, Methyl 4-methoxybenzoate 4-(Methoxycarbonyl)anisole Methyl 4-Methoxybenzyl 4-Methoxybenzoic Acid Methyl Ester p-Anisic Acid Methyl Ester Methyl 4-Methoxybenzoate 4-methoxy-benzoicacimethylester Benzoic acid, p-methoxy-, methyl ester Benzoicacid,4-methoxy-,methylester Methyl ester of p-Methoxybenzoic acid p-Methoxybenzoic acid methyl ester p-methoxy-benzoicacimethylester 4-METHOXYBENZOIC ACID METHYL ESTER METHYL P-METHOXYBENZOATE METHYL P-ANISATE METHYL PARA-ANISATE METHYL 4-ANISATE METHYL 4-METHOXYBENZOATE METHYL ANISATE FEMA 2679 ANISIC ACID METHYL ESTER METHYL P-ANISATE 99+% 4-Methoxybenzoicacidmethylester~Methylp-anisate 4-METHOXYLBENZOICACIDMETHYLESTER PARA-METHYLANISATE benzenecarboperoxoic acid ethyl ester Methyl Salicylate Impurity 4(Methyl Salicylate EP Impurity D） Salicylic Acid Impurity 2(methyl p-anisate) Methylp-Anisate> Miconazole Impurity 7 Methyl anisate USP/EP/BP Methyl-4-Methoxy Benzoate (Methyl-P-Anisate) 98% Methyl 4-methoxybenzoate , Methyl anisate Doltenol Impurity 5091-7F 121-98-2 191-98-2 CH3OC6H4COOCH3 C8 to C9 Carbonyl Compounds Building Blocks Organic Building Blocks Esters Aromatic Esters bc0001