2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
- CAS No.
- 69563-88-8
- Chemical Name:
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
- Synonyms
- HFBAPP;4-BDAF;BAPOFP;6FBAPP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
- CBNumber:
- CB3265411
- Molecular Formula:
- C27H20F6N2O2
- Molecular Weight:
- 518.45
- MDL Number:
- MFCD00015723
- MOL File:
- 69563-88-8.mol
Melting point | 159-163 °C(lit.) |
---|---|
Boiling point | 544.8±50.0 °C(Predicted) |
Density | 1.3455 (estimate) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | Soluble in DMSO |
Water Solubility | Insoluble in water |
form | powder to crystal |
pka | 4.80±0.10(Predicted) |
color | White to Almost white |
InChIKey | HHLMWQDRYZAENA-UHFFFAOYSA-N |
CAS DataBase Reference | 69563-88-8(CAS DataBase Reference) |
EPA Substance Registry System | Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 22-36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | CY1213000 | |||||||||
HazardClass | IRRITANT | |||||||||
HS Code | 29222990 | |||||||||
NFPA 704 |
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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE price More Price(40)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 386669 | 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97% | 69563-88-8 | 5g | $82.6 | 2024-03-01 | Buy |
TCI Chemical | B1398 | 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane >98.0%(HPLC)(T) | 69563-88-8 | 5g | $57 | 2024-03-01 | Buy |
TCI Chemical | B1398 | 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane >98.0%(HPLC)(T) | 69563-88-8 | 25g | $188 | 2024-03-01 | Buy |
Tocris | 6689 | GI530159 ≥99%(HPLC) | 69563-88-8 | 50 | $516 | 2021-12-16 | Buy |
Tocris | 6689 | GI530159 ≥99%(HPLC) | 69563-88-8 | 10 | $122 | 2021-12-16 | Buy |
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Uses,Production
Uses
2,2-bis[4-(4-Aminophenoxy)phenyl]hexafluoropropane (cas# 69563-88-8) has been used in the preparation of permeable membranes for atmospheric CO2 capture and gas transport.
Description
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].
Chemical Properties
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder
Uses
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.
Hazard
Moderately toxic by ingestion and skin contact. An eye irritant.
storage
Store at +4°C
References
[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Chengdu Yuanda Chemical Co., Ltd | 28-85356300 +8618980937689 | sales@ydachem.com | CHINA | 94 | 58 |
Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
Heynova (Shanghai) New Material Technology CO., Ltd | +86-17821320848; +8617821320848 | zoe@heynovachem.com | China | 179 | 58 |
CHINATECH(TIANJIN) CHEMICAL CO.,LTD. | +86-86-18222493702 +8618222493702 | sales8@chinatechem.com | China | 64 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12825 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18275 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20288 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18648 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21639 | 55 |
View Lastest Price from 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-10-25 | 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
|
US $0.00 / kg | 1kg | 99% | 20 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2024-10-24 | 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
|
US $0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | ||
2024-09-09 | 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP)
69563-88-8
|
US $0.00 / KG | 1KG | 99% | 1500KG/month | Shanghai Daken Advanced Materials Co.,Ltd |
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
- US $0.00 / kg
- 99%
- Hebei Yanxi Chemical Co., Ltd.
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
- US $0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP)
69563-88-8
- US $0.00 / KG
- 99%
- Shanghai Daken Advanced Materials Co.,Ltd
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Spectrum
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