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ChemicalBook >> CAS DataBase List >>2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

CAS No.
69563-88-8
Chemical Name:
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
Synonyms
HFBAPP;4-BDAF;BAPOFP;6FBAPP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
CBNumber:
CB3265411
Molecular Formula:
C27H20F6N2O2
Molecular Weight:
518.45
MDL Number:
MFCD00015723
MOL File:
69563-88-8.mol
Last updated:2024-10-24 21:11:45

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Properties

Melting point 159-163 °C(lit.)
Boiling point 544.8±50.0 °C(Predicted)
Density 1.3455 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in DMSO
Water Solubility Insoluble in water
form powder to crystal
pka 4.80±0.10(Predicted)
color White to Almost white
InChIKey HHLMWQDRYZAENA-UHFFFAOYSA-N
CAS DataBase Reference 69563-88-8(CAS DataBase Reference)
EPA Substance Registry System Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  CY1213000
HazardClass  IRRITANT
HS Code  29222990
NFPA 704
0
2 0

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 386669 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97% 69563-88-8 5g $82.6 2024-03-01 Buy
TCI Chemical B1398 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane >98.0%(HPLC)(T) 69563-88-8 5g $57 2024-03-01 Buy
TCI Chemical B1398 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane >98.0%(HPLC)(T) 69563-88-8 25g $188 2024-03-01 Buy
Tocris 6689 GI530159 ≥99%(HPLC) 69563-88-8 50 $516 2021-12-16 Buy
Tocris 6689 GI530159 ≥99%(HPLC) 69563-88-8 10 $122 2021-12-16 Buy
Product number Packaging Price Buy
386669 5g $82.6 Buy
B1398 5g $57 Buy
B1398 25g $188 Buy
6689 50 $516 Buy
6689 10 $122 Buy

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Uses,Production

Uses

2,2-bis[4-(4-Aminophenoxy)phenyl]hexafluoropropane (cas# 69563-88-8) has been used in the preparation of permeable membranes for atmospheric CO2 capture and gas transport.

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].

Chemical Properties

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder

Uses

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.

Hazard

Moderately toxic by ingestion and skin contact. An eye irritant.

storage

Store at +4°C

References

[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.

1478-61-1
100-00-5
69563-88-8
Synthesis of 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE from Hexafluorobisphenol A and 4-Chloronitrobenzene

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 270)Suppliers
Supplier Tel Email Country ProdList Advantage
Chengdu Yuanda Chemical Co., Ltd
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Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58
Heynova (Shanghai) New Material Technology CO., Ltd
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CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
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Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12825 58
Hebei Weibang Biotechnology Co., Ltd 		+8617732866630 bess@weibangbio.com China 18275 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20288 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18648 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21639 55

View Lastest Price from 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE pictures 2024-10-25 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
 US $0.00 / kg 1kg 99% 20 tons Hebei Yanxi Chemical Co., Ltd.
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE pictures 2024-10-24 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
69563-88-8
 US $0.00 / KG 1KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) pictures 2024-09-09 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP)
69563-88-8
 US $0.00 / KG 1KG 99% 1500KG/month Shanghai Daken Advanced Materials Co.,Ltd
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-HEXAFLUOROPROPANANE 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane, 4,4μ-(Hexafluoroisopropylidene)bis(p-phenylenoxy)dianiline HFBAPP 2,2-Bis[4-(4-aminophenoxyphenyl)]hexafluoropropane 98% 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUOROPROPANE 2,2-Bis[4-(4-aminophenoxyphenyl])hexafluoropropane98% 2,2''-BIS[4-(4-AMINOPHENOXY)PHENY]HEXAFLUOROPROPANE 4,4'-[HEXAFLUOROISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(P-PHE NYLENOXY)DIANILINE 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS[(4-AMINOPHENOXY)BENZENE] 4'',4'''-(HEXAFLUOROISOPROPYLIDENE)BIS(4-PHENOXYANILINE) 4',4'''-(HEXAFLUOROISOPROPYLIDENE)-BIS-(4-PHENOXYANILINE) 4-BDAF isbenzenamine leneoxy))bis- leneoxy)]bis- 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane [4-[4-[1-[4-(4-aminophenoxy)phenyl]-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenoxy]phenyl]amine 4-[4-[2-[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]aniline 4-[4-[2-[4-(4-azanylphenoxy)phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-yl]phenoxy]aniline 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane ,99% 2,2-BIS[4-(4-AMINOPH BAPOFP 2,2-Bis[4-(-aMinophenoxy)phenyl]hexafluoropropane(HFBAPP) 4,4'-{(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis[(benzene-4,1-diyl)oxy]}dianiline, BIS-AF-A, 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 2,2- double[4-(4- aMinophenoxy)]six fluorinepropane 2,2-Bis[4-(-aminophenoxy)phenyl]hexafluoropropane 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (HFBAPP) 4,4'-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))dianiline 2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 4′ 4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline) 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) BIS-AF-A 4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-phenyleneoxy))b benzenamine,4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-pheny benzenamine,4,4’-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-pheny 4-(4-aminophenoxy)phenyl 6FBAPP 2,2'-Bis[4-(4- aminophenoxy)-1,1,1,3,3,3-sixfluoropropane(HFBAPP) 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97% GI 530159 4,4'-[[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis[benzenamine] 4-[2-(4-amino-2-phenoxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-3-phenoxyaniline 2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane > Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE ISO 9001：2015 REACH 2,2-Bis[4-(4-aminophenoxy) 2,2-bi [4-(4-aminophenoxy)benzeneHexafluoropropane 2,2-double [4-4-aminophenoxy)phenyl]Hexafluoropropane 2,2-Bis[4-(4-aminophenoxybenzene)]hexafluoropropane, 97% 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 2,2- Bis[ 4-(4-aminophenoxy)pheny] hexafluoropropane (HFBAPP) 69563-88-8 6956-88-8 C27H20F6N2O2 CF32CC6H4OC6H4NH22 Reagent for High-Performance Polymer Research