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2',4',6'-Trihydroxyacetophenone monohydrate

2',4',6'-Trihydroxyacetophenone monohydrate structure

CAS No.: 480-66-0

Chemical Name:: 2',4',6'-Trihydroxyacetophenone monohydrate

Synonyms: THAP;Phloracetophenone;PHLOROACETOPHENONE;Monoacetylphloroglucinol;2-Acetylphloroglucinol hydrate;2',4',6'-TRIHYDROXYACETOPHENONE;2,4,6-trihydroxylacetophenone monohydrate;NSC 54927;Phloracetophene;Acetophloroglucine

CBNumber:: CB2333652

Molecular Formula:: C8H8O4

Molecular Weight:: 168.15

MDL Number:: MFCD00002287

MOL File:: 480-66-0.mol

MSDS File:: SDS

Last updated:2024-12-18 14:07:02

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2',4',6'-Trihydroxyacetophenone monohydrate Properties

Melting point	219-221 °C(lit.)
Boiling point	257.07°C (rough estimate)
Density	1.3037 (rough estimate)
refractive index	1.5090 (estimate)
storage temp.	Store below +30°C.
solubility	DMSO (Sparingly), Ethanol (Slightly), Methanol (Slightly), Water (Very Slightly,
pka	7.76±0.23(Predicted)
form	Powder
color	light yellow
Water Solubility	Soluble in water.
BRN	1911197
Stability	Stable under recommended storage conditions., Stable Under Recommended Storage C
LogP	1.472 (est)
CAS DataBase Reference	480-66-0(CAS DataBase Reference)
FDA UNII	8L7XD8830T
NIST Chemistry Reference	Ethanone, 1-(2,4,6-trihydroxyphenyl)-(480-66-0)
EPA Substance Registry System	Ethanone, 1-(2,4,6-trihydroxyphenyl)- (480-66-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H303-H315-H319-H335

Precautionary statements

P280g-P261-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-24/25

WGK Germany

RTECS

AN0528000

TSCA

Yes

HazardClass

IRRITANT

HS Code

29145000

NFPA 704

	0
2		0

2',4',6'-Trihydroxyacetophenone monohydrate price More Price(44)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	T1888	2',4',6'-Trihydroxyacetophenone Monohydrate >98.0%(GC)	480-66-0	5g	$79	2024-03-01	Buy
TCI Chemical	T1888	2',4',6'-Trihydroxyacetophenone Monohydrate >98.0%(GC)	480-66-0	25g	$244	2024-03-01	Buy
Alfa Aesar	L04156	2',4',6'-Trihydroxyacetophenone hydrate, 98+%	480-66-0	5g	$39.65	2024-03-01	Buy
Alfa Aesar	L04156	2',4',6'-Trihydroxyacetophenone hydrate, 98+%	480-66-0	25g	$110.65	2024-03-01	Buy
Cayman Chemical	19451	Monoacetylphloroglucinol ≥98%	480-66-0	10g	$49	2021-12-16	Buy

Product number	Packaging	Price	Buy
T1888	5g	$79	Buy
T1888	25g	$244	Buy
L04156	5g	$39.65	Buy
L04156	25g	$110.65	Buy
19451	10g	$49	Buy

2',4',6'-Trihydroxyacetophenone monohydrate Chemical Properties,Uses,Production

Chemical Properties

Light Brown Solid

Uses

Induced choleresis in rats is mediated through multidrug resistance protein-2 (Mrp2). It enhances bile secretion.

Uses

Monoacetylphloroglucinol (MAPG) is small molecular weight phenolic metabolite belonging to the phloroglucinol (1,3,5-trihydroxybenzene) family, produced by bacteria including Pseudomonas strains. MAPG exhibits a broad range of biological activity albeit with mostly low potency. In the search for novel actives, MAPG and related metabolites are important metabolites for dereplication to eliminate leads due to high amounts of weakly potent actives. Although weakly active, this family appears to be important in the biocontrol of plant diseases by some Pseudomonas strains.

Preparation

Preparation by reaction of acetic anhydride on phloroglucinol,
with concentrated sulfuric acid at 130° (70%)
with boron trifluoride at 10° (62.5–68%)
with zinc chloride at 145–150° (50%)
with Amberlite IR-120 or Zeokarb 225 (cation exchange resins, sulfonic acid type) at 160° (39%).

Definition

ChEBI: A benzenetriol that is acetophenone in which the hydrogens at positions 2, 4, and 6 on the phenyl group are replaced by hydroxy groups. It is used as a matrix in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry for the analysis of acid c glycans and glycopeptides.

Biological Activity

monoacetylphloroglucinol (mapg), small molecular weight phenolic metabolite, is produced via bacteria including pseudomonas strains. mapg is acetylated to form the broad-spectrum antibiotic, 2,4-diacetylphloroglucinol (dapg) by mapg acetyltransferase. in addition, mapg exerts fairly weak potency when exhibiting a broad range of antibiotic activity. even though weakly active, it seems that mapg is essential in the biocontrol of plant diseases by some pseudomonas strains [1].

target

HMG-CoA Reductase

Purification Methods

Crystallise the ketone from hot H2O (35mL/g). [Beilstein 8 IV 2729.]

References

[1]. hayashi, a., saitou, h., mori, t., matano, i., sugisaki, h., & maruyama, k. molecular and catalytic properties of monoacetylphloroglucinol acetyltransferase frompseudomonassp. ygj3. bioscience, biotechnology, and biochemistry. 2012; 76(3): 559-566.

2',4',6'-Trihydroxyacetophenone monohydrate synthesis

Synthesis of 2',4',6'-Trihydroxyacetophenone monohydrate from Phloroglucinol and Acetonitrile

2',4',6'-Trihydroxyacetophenone monohydrate Preparation Products And Raw materials

Raw materials

Preparation Products

3,4-Dimethoxyphenol 1-(3-ACETYL-2,4,6-TRIHYDROXYPHENYL)ETHAN-1-ONE Desmethylanhydroicaritin Licoflavone C 2-NITROPHLOROGLUCINOL

2',4',6'-TRIMETHOXYACETOPHENONE Isolicoflavonol Mulberrin 4-Ethylresorcinol 4H-1-Benzopyran-4-one, 5,8-dihydroxy-7-methoxy-2-(2-methoxyphenyl)-

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2',4',6'-Trihydroxyacetophenone monohydrate Suppliers

Global( 418)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8810	58
Shaanxi Dideu Medichem Co. Ltd	18192627656	1012@dideu.com	China	3003	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29880	58
HaBo Hong Kong Co., Limited.	+86-25-18512596065	info@habotech.com	CHINA	933	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	17777	58
Shandong chuangyingchemical Co., Ltd.	18853181302	sale@chuangyingchem.com	CHINA	5906	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58

Supplier	Advantage
Hebei Weibang Biotechnology Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
career henan chemical co	58
HaBo Hong Kong Co., Limited.	58
Accela ChemBio Inc.	58
Shandong chuangyingchemical Co., Ltd.	58
Chongqing Chemdad Co., Ltd	58

View Lastest Price from 2',4',6'-Trihydroxyacetophenone monohydrate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-26	2',4',6'-Trihydroxyacetophenone monohydrate 480-66-0	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Weibang Biotechnology Co., Ltd
2024-11-16	Phloracetophenone 480-66-0	US $29.00 / mL		99.26%	10g	TargetMol Chemicals Inc.
2024-08-19	2-Acetylphloroglucinol hydrate 480-66-0	US $1.00-100.00 / KG	1KG	95%	300KG	Shaanxi Dideu Medichem Co. Ltd

2',4',6'-Trihydroxyacetophenone monohydrate
480-66-0
US $0.00-0.00 / KG
99%
Hebei Weibang Biotechnology Co., Ltd

Phloracetophenone
480-66-0
US $29.00 / mL
99.26%
TargetMol Chemicals Inc.

2-Acetylphloroglucinol hydrate
480-66-0
US $1.00-100.00 / KG
95%
Shaanxi Dideu Medichem Co. Ltd

2',4',6'-Trihydroxyacetophenone monohydrate Spectrum

2',4',6'-Trihydroxyacetophenone monohydrate(480-66-0)MS 2',4',6'-Trihydroxyacetophenone monohydrate(480-66-0)IR1 2',4',6'-Trihydroxyacetophenone monohydrate(480-66-0)IR2

480-66-0(2',4',6'-Trihydroxyacetophenone monohydrate)Related Search:

Acetophenone MELIBIOSE 3,5-Dihydroxyacetophenone 2-HYDROXYACETOPHENONE 2',6'-Dihydroxyacetophenone

3'-Hydroxyacetophenone 2,4-Dihydroxyacetophenone 4-Nitroacetophenone 4'-(Trifluoromethyl)acetophenone 3-Aminoacetophenone

4'-Hydroxyacetophenone 3,4-Dihydroxyacetophenone 2'-Hydroxyacetophenone 4'-Bromoacetophenone 2',4'-Dichloroacetophenone

3-Nitroacetophenone Chloral hydrate Rutin

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2',4',6'-Trihydroxyacetophenone monohydrate Phloroacetophenone monohydrate 2',4',6'-Trihydroxyacetophenone (monohydrate/anhydrous) 2',4',6'-Trihydroxyacetophenone hydrate, 98+% 1-(2,4,6-TRIHYDROXYPHENYL)-ETHANONE Acetophenone,2’,4’,6’-trihydroxy- Acetophloroglucine Acetylphloroglucinol Ethanone,1-(2,4,6-trihydroxyphenyl)- Phloracetophene Phloroacetophenonehydrate 2,4,6-TRIHYDROXYACETOPHENONE(PHLOROACETOPHENONE) 2,4,6-Trihydroxyaetcophenone 2,4,6-TRIHYDROXYACETOPHENONE MONOHYDRATE, PGE. WITH 10X10 MG 2,4,6-TRIHYDROXYLACETOPHENONE NSC 54927 2',4',6'-Trihydroxyacetophenone,98% 2-Acetylphloroglucinol, THAP 1-(2,4,6-tTihydroxyphenyl)ethanone 2,4,6-Trihydroxy-1-acetylbenzene Methyl-(2,4,6-trihydroxyphenyl) ketone 2',4',6'-Trihydroxya 1-(2,4,6-Trihydroxyphenyl)ethan-1-one, 2-Acetylbenzene-1,3,5-triol 1-(2,4-dihydroxyphenyl)-2-hydroxyethan-1-one 2-Acetylphloroglucinol Phloroacetophenone 1-(2,4,6-trihydroxyphenyl)ethanone hydrate 2',4', 6'-Trihydroxyacetophenone Monohydrat 2',4',6'-trihydroxyacetopheMone Acetophenone, 2',4',6'-trihydroxy- (8CI) 1-(2,4,6-trihydroxyphenyl)-ethanon 2,4,6-Trihydroxyacetophenon 2,4,6-TrihydroxyacetophenonMonohydrat 2,4,6-trihyroxyacetophenone 2-Acetyl-1,3,5-trihydroxybenzene 2-Acetylphloroglucin Acetophenone, 2',4',6'-trihydroxy- 6'-Trihydroxyacetophenone 2-(2,4-dihydroxyphenyl)-2-hydroxy-1-phenylethanone JR-13799, 1-(2,4,6-Trihydroxyphenyl)ethanone hydrate, 98% 2,4,6-Trihydroxyacetophenone.H2O 2',4',67-TRIHYDROXYACETOPHENONE MONOHYDR Phloroglucinol Acetyl 2-Acetylphloroglucinol hydrate THAP 2',4',6'-TRIHYDROXYACETOPHENONE Phloracetophenone PHLOROACETOPHENONE Monoacetylphloroglucinol 2,4,6-trihydroxylacetophenone monohydrate Phloracetophenone/2',4',6'-Trihydroxyacetophenone 1-(2,4,6-trihydroxyphenyl)ethan-1-one 2',4',6'-Trihydroxyacetophenone 2',4',6'-Trihydroxyacetophenon 2’,4’,6’-Trihydroxyacetophenone-98% 480-66-0 C8H8O4xH2O HO3C6H2COCH3H2O Ketones

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2',4',6'-Trihydroxyacetophenone monohydrate

2',4',6'-Trihydroxyacetophenone monohydrate Properties

SAFETY

Risk and Safety Statements

2',4',6'-Trihydroxyacetophenone monohydrate price More Price(44)

2',4',6'-Trihydroxyacetophenone monohydrate Chemical Properties,Uses,Production

Chemical Properties

Uses

Uses

Preparation

Definition

Biological Activity

target

Purification Methods

References

2',4',6'-Trihydroxyacetophenone monohydrate synthesis

2',4',6'-Trihydroxyacetophenone monohydrate Preparation Products And Raw materials

Raw materials

Preparation Products

2',4',6'-Trihydroxyacetophenone monohydrate Suppliers

View Lastest Price from 2',4',6'-Trihydroxyacetophenone monohydrate manufacturers

2',4',6'-Trihydroxyacetophenone monohydrate Spectrum

480-66-0(2',4',6'-Trihydroxyacetophenone monohydrate)Related Search: