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ChemicalBook >> CAS DataBase List >>Terpinyl acetate

Terpinyl acetate

CAS No.
80-26-2
Chemical Name:
Terpinyl acetate
Synonyms
Terpenyl acetate;Terpineol acetate;ALPHA-TERPINYL ACETATE;a-Terpinyl acetate;à-terpinyl acetate;p-Menth-1-en-8-yl acetate;FEMA 3047;TERPINYL ACETATE;Terpinyl Acctate;yisuansongyouzhi
CBNumber:
CB2161886
Molecular Formula:
C12H20O2
Molecular Weight:
196.29
MDL Number:
MFCD00037155
MOL File:
80-26-2.mol
Last updated:2024-12-18 14:07:02

Terpinyl acetate Properties

Melting point 112-113.5 °C
Boiling point 220 °C (lit.)
Density 0.953 g/mL at 25 °C (lit.)
vapor pressure 3.515Pa at 23℃
FEMA 3047 | TERPINYL ACETATE (ISOMER MIXTURE)
refractive index n20/D 1.465(lit.)
Flash point >230 °F
storage temp. Store at -20°C
solubility DMSO : 100 mg/mL (509.45 mM; Need ultrasonic)
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.96
Odor at 100.00 %. herbal bergamot lavender lime citrus
Odor Type herbal
Water Solubility 23mg/L at 23℃
JECFA Number 368
BRN 3198769
LogP 4.4 at 30℃
CAS DataBase Reference 80-26-2(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) TERPINYL ACETATE
FDA 21 CFR 172.515
EWG's Food Scores 1
FDA UNII 9RXE0I9F2J
NIST Chemistry Reference 3-Cyclohexene-1-methanol, «alpha»,«alpha»,4-trimethyl-, acetate(80-26-2)
EPA Substance Registry System .alpha.-Terpinyl acetate (80-26-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS09
Signal word  Warning
Hazard statements  H411
Precautionary statements  P273-P391-P501
Hazard Codes  Xi
Risk Statements  36/38
Safety Statements  26-36
WGK Germany  2
RTECS  OT0200000
TSCA  Yes
HS Code  29153900
Toxicity The acute oral LD50 value in rats was reported as 5.075 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).
NFPA 704
2
0 0

Terpinyl acetate price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W304799 α-Terpinyl acetate FG 80-26-2 1kg $174 2024-03-01 Buy
Sigma-Aldrich W304799 α-Terpinyl acetate FG 80-26-2 5kg $743 2024-03-01 Buy
Sigma-Aldrich W304799 α-Terpinyl acetate FG 80-26-2 10Kg $1330 2024-03-01 Buy
Sigma-Aldrich 09206 (±)-α-Terpinyl acetate, predominantly α-isomer analytical standard 80-26-2 1ml $108 2024-03-01 Buy
TCI Chemical T0023 Terpinyl Acetate >85.0%(GC) 80-26-2 25mL $17 2024-03-01 Buy
Product number Packaging Price Buy
W304799 1kg $174 Buy
W304799 5kg $743 Buy
W304799 10Kg $1330 Buy
09206 1ml $108 Buy
T0023 25mL $17 Buy

Terpinyl acetate Chemical Properties,Uses,Production

Chemical Properties

The enantiomers and the racemate occur in many essential oils (e.g., Siberian pine-needle oil and cypress oil), but generally not as the main component. Pure Terpinyl acetate are colorless liquids with a fresh bergamot–lavender odor. Commercially available terpinyl acetate consists mainly of alpha-terpinyl acetate, but also contains a number of other isomeric compounds such as beta-terpinyl acetate. It can be prepared by acetylating the terpineol mixture obtained from terpin hydrate, using a customary procedure for tertiary alcohols.
Because of its odor properties, stability, and low price, large quantities of terpinyl acetate are used in perfumery for lavender and bergamot types, as well as in essential oil reconstitutions.

Physical properties

Terpinyl acetate is a p-menthane monoterpenoid that naturally found in melanoleuca, elettaria cardamomum. It is a colorless liquid with a bergamot, bergamot odor. Soluble in five or more volumes of 70% alcohol; slightly soluble in water and glycerol. Combustible.

Occurrence

Reported in over 40 essential oils, including cypress, Malabar cardamom, cajeput niaouli, Siberian pine needles, pine, Melaleuca trichostachya, Melaleuca pauciflora and others; also identified in the essential oils of bitter orange (Fenarolfs Handbook of Flavor Ingredients, 1971 ; Gildemeister & Hoffman, 1966). Terpinyl Acetate is found in Pine oil, Cajeput oil, Pine needle oil, Cardamom oil and other essential oils.

Uses

Perfumes, flavoring agent.

Definition

ChEBI: Alpha-Terpinyl acetate is a p-menthane monoterpenoid.

Preparation

Terpinyl acetate was successfully synthesized from (x-terpineol and acetic anhydride in supercritical carbon dioxide (SC-C02) by enzymatic catalysis.
By acetylation of a-terpineol or mixed isomeric terpineols (Bedoukian, 1967).

Synthesis Reference(s)

Tetrahedron, 38, p. 1843, 1982 DOI: 10.1016/0040-4020(82)80261-5

General Description

Α-Terpinyl acetate, a monoterpene ester, is a commercially important fragrance molecule. It can be prepared from α-pinene in the presence of H-beta zeolite catalysts. The essential oils obtained from Stachys setifera ssp. iranica, Chamaecyparis obtuse leaves and Thymus willkomii contain Α-terpinyl acetate as one of the main components.

Flammability and Explosibility

Non flammable

Safety Profile

Mildly toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Global( 367)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Weibang Biotechnology Co., Ltd 		+8615531157085 abby@weibangbio.com China 8810 58
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View Lastest Price from Terpinyl acetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Terpinyl acetate pictures 2024-12-20 Terpinyl acetate
80-26-2
 US $100.00 / kg1 1kg1 99 5000 Hebei Zhuanglai Chemical Trading Co.,Ltd
Terpinyl acetate pictures 2024-12-13 Terpinyl acetate
80-26-2
 US $0.00 / KG 25KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Terpinyl acetate pictures 2024-11-27 Terpinyl acetate
80-26-2
 US $10.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
  • Terpinyl acetate pictures
  • Terpinyl acetate
    80-26-2
  • US $100.00 / kg1
  • 99
  • Hebei Zhuanglai Chemical Trading Co.,Ltd

Terpinyl acetate Spectrum

MENTHEN-1-YL-8-PROPIONATE FEMA 3047 (+/-)-2-(4-METHYL-3-CYCLOHEXENYL)ISOPROPYL ACETATE ACETIC ACID TERPINYL ESTER (+/-)-ALPHA-TERPINYL ACETATE TERPINYL ACETATE TERPINYL ACETATE AP 3-CYCLOHEXENE-1-METHANOL, ALPHA, ALPHA, 4-TRIMETHYL:ACETATE 1-Methyl-1-(4-methyl-3-cyclohexen-1-yl)ethyl acetate 2-(4-Methyl-3-cyclohexenyl)-2-propylAcetate 4-Terpinyl acetate alpha,alpha,4-trimethyl-3-cyclohexene-1-methanoacetate Alpha-Terpenyl acetate alpha-terpinenyl acetate alpha-Terpineol acetate alpha-terpineol,acetate p-Menth-1-en-8-ol, acetate p-menth-1-en-8-ol,acetate terpinenyl acetate P-MENTH-1-ENE-8-YL ACETATE Terpinyl acetate, Mixture of isoMers (±)-α-Terpinyl acetate, predominantly α-isomer (+/-)-alpha-Terpinyl acetate, predominantly alpha-isomer technical, >=90% (GC) menth-1-en-8-yl acetate TERPINYL ACETATE 95+% MIXTURE OF ISOM& Terpinyl Acetate Q1 terpinylacetate,α-terpineolacetate TERPINYL ACETATE(SG) p-Menth-1-en-8-ylacetat TERPINYLACETAT MIN. 98 P. ESTERGEHALT 3-Cyclohexene-1-methanol, .alpha., TERPINYL ACETATE WITH GC ɑ-Terpinyl acetate, tech. 90% TERPINYL ACETATE, NATURAL (±)-α-Terpinyl acetate, (±)-2-(4-Methyl-3-cyclohexenyl)isopropyl acetate (4-Methyl-1-propan-2-yl-1-cyclohex-2-enyl) acetate 2-(4-Methyl-3-cyclohexen-1-yl)-2-propyl acetate 3-Cyclohexene-1-methanol, a,a,4-trimethyl-, acetate a-Terpineol acetate a-Terpinyl ethanoate p-Menth-1(7)-en-8-ol acetate α,α-Dimethyl-4-methylenecyclohexanemethanol acetate Acetic acid p-menth-1-en-8-yl ester p-Mentha-1-ene-8-ol acetate α,α,4-Trimethyl-3-cyclohexene-1-methanol acetate ^a-Terpinyl acetate, tech. 90% alpha-Terpinyl acetate, tech. 90% Terpinyl acetate,(±)-α-Terpinyl acetate, (±)-2-(4-Methyl-3-cyclohexenyl)isopropyl acetate Terpinyl acetate, 90%, mixture of isomers Terpinyl acetate 98% Terpinyl Acctate yisuansongyouzhi 3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, 1-acetate TerpinylAcetate> 3-Cyclohexene-1-methanol, α,α,4-trimethyl-, 1-acetate (+/-)-alpha-Terpinyl acetate, predominantly alpha-isomer Terpinyl acetate USP/EP/BP High quality Terpinyl acetate CAS 80-26-2