ChemicalBook >> CAS DataBase List >>Chloroform-d
Chloroform-d
- CAS No.
- 865-49-6
- Chemical Name:
- Chloroform-d
- Synonyms
- deuterated chloroform;CHLOROFORM-D1;Deuteriochloroform;Deuterotrichloromethane;Methane-d, trichloro-;Chloroform-d, 99.8 atom % D, anhydrous;CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS);Chloroform-d,for NMR,100.0 atom % D, packagedin 0.50 ml ampules;oroform-d;d,ChloroforM
- CBNumber:
- CB2103569
- Molecular Formula:
- CCl3D
- Molecular Weight:
- 120.38
- MDL Number:
- MFCD00000827
- MOL File:
- 865-49-6.mol
- MSDS File:
- SDS
Last updated:2024-04-22 11:58:20
| Melting point | −64 °C(lit.) |
|---|---|
| Boiling point | 60.9 °C(lit.) |
| Density | 1.500 g/mL at 25 °C(lit.) |
| vapor pressure | 211 hPa (20 °C) |
| refractive index |
n |
| Flash point | 62°C |
| storage temp. | Store at +2°C to +8°C. |
| solubility | Miscible with organic solvents, ethyl acetate and acetone. |
| form | Liquid |
| color | White to beige |
| Specific Gravity | 1.505 |
| Sensitive | Moisture Sensitive |
| BRN | 1697633 |
| Exposure limits |
ACGIH: TWA 10 ppm OSHA: Ceiling 50 ppm(240 mg/m3) NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3) |
| Stability | Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents. |
| InChIKey | HEDRZPFGACZZDS-MICDWDOJSA-N |
| LogP | 1.5-1.6 at 20-23℃ and pH9 |
| Surface tension | 72.3mN/m at 998.5mg/L and 20℃ |
| CAS DataBase Reference | 865-49-6(CAS DataBase Reference) |
| FDA UNII | P1NW4885VT |
| EPA Substance Registry System | Chloroform-d (865-49-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H319-H331-H336-H351-H361d-H372 | |||||||||
| Precautionary statements | P201-P301+P312-P302+P352-P304+P340+P311-P305+P351+P338-P308+P313 | |||||||||
| Hazard Codes | Xn,T | |||||||||
| Risk Statements | 22-38-40-48/20/22-48/20-36/38-20/22-63 | |||||||||
| Safety Statements | 36/37 | |||||||||
| RIDADR | UN 1888 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28459000 | |||||||||
| Toxicity | LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg | |||||||||
| NFPA 704 |
|
Chloroform-d price More Price(102)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 151823 | Chloroform-d 99.8 atom % D | 865-49-6 | 10x0.6ml | $38.4 | 2024-03-01 | Buy |
| Sigma-Aldrich | 151823 | Chloroform-d 99.8 atom % D | 865-49-6 | 10x0.75ml | $40.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 1.03420 | Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv? | 865-49-6 | 25mL | $43.4 | 2024-03-01 | Buy |
| Sigma-Aldrich | 1.03420 | Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv? | 865-49-6 | 100mL | $109 | 2024-03-01 | Buy |
| Sigma-Aldrich | 1.03420 | Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv? | 865-49-6 | 500mL | $449 | 2024-03-01 | Buy |
Chloroform-d Chemical Properties,Uses,Production
Water peak
The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.
Application
Reagents for nuclear magnetic instruments
Chemical Properties
colourless liquid
Uses
Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).
Uses
Labelled Chloroform, generally in trimethylsilane solution, used in NMR spectroscopy as a solvent. Unlabelled chloroform has been used an an anaesthetic due to its action on the central nervous system .
Uses
Chloroform-d is widely used in the organic solvent for the NMR analysis.
Definition
ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.
General Description
Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.
Chloroform-d Preparation Products And Raw materials
Global( 213)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Peric Technology Co.,Ltd | +86-0310-7183483 +8615030098277 | jiake718@aliyun.com | China | 36 | 58 |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | sales@ichemie.com | China | 998 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20288 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21638 | 55 |
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| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
View Lastest Price from Chloroform-d manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-24 | Chloroform-d
865-49-6
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-11-01 | Chloroform-D
865-49-6
|
US $0.00 / kg | 200kg | 99% | plenty of stock | Hangzhou ICH Biofarm Co., Ltd | |
 |
2022-02-25 | Chloroform-d
865-49-6
|
US $100.00 / KG/Tin | 1KG | 99% | 10Tons | Hebei Senko Biotechnology Co., Ltd. |
-
- Chloroform-d
865-49-6
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Chloroform-D
865-49-6
- US $0.00 / kg
- 99%
- Hangzhou ICH Biofarm Co., Ltd
-
- Chloroform-d
865-49-6
- US $100.00 / KG/Tin
- 99%
- Hebei Senko Biotechnology Co., Ltd.
865-49-6(Chloroform-d)Related Search:
Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate
5α-Cholestane
NMR REF STD, 0.0485M TRIPHENYLPHOSPHATE IN CHLOROFORM-D, 99.9 ATOM % D,NMR REF STD, 0.0485M TRIPHENYLPHOSPHATEIN CHLOROFORM-D,99.8 ATOM % D
PHENOL:CHLOROFORM:ISOAMYLALCOHOL 49.5:49 .5:1,PHENOL:CHLOROFORM:ISOAMYL ALC. 125:24:1, FOR MOL. BIOLOGY
BETA-SITOSTEROL 1X1ML CHLOROFORM 100UG/M L
Dichloromethane
100 MG/ML CHOLESTERYL ACETATE IN CHLOROFORM-D
Chloroform
Chloroform-d
DICHLOROMETHANE D
1of4
Chloroform-d, contains 0.03 v/v% TMS, 99.8+ atom % D, AcroSeal, for NMR
ChloroforM-d, for NMR, 99.8 atoM % D, packaged in 0.75 Ml aMpoules
CHLORAL HYDRATE SOLUTION PHE
CONGO RED PAPER PHE
COPPER EDETATE SOLUTION PHE
GC TEMPASE 2X MASTER MIX I 2500R
GC TEMPASE 2X MASTER MIX I 500R
GC TEMPASE 2X MASTER MIX II 500R
Chloroform-d, 99.8% Isotopic, contains 1% TMS
Chloroform-d, 100% Isotopic, contains 0.03% TMS
Chloroform-d, 99.8% Isotopic, contains 0.03% TMS
CHLOROFORM-D, "100%", 99.96 ATOM % D, CO
CHLOROFORM-D, >=99.8 ATOM % D, CONTA
CHLOROFORM-D, 99.8 ATOM % D, CONTAINS 0&
Chloroform-D1 with TMS (1 vol.%), deuteration degree min. 99.5 % for NMR spectroscopy (stabilized with silver) MagniSolv
Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv
Chloroform-D1 0.03 vol.% TMS, deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv
Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy MagniSolv
Chloroform-D1 deuteration degree min. 99.96% for NMR spectroscopy MagniSolv
Chloroform-d, Isotopic
Chloroform - D1, Stabilized with silver
Chloroform - D1, 0.03 vol.% TMS, Stabilized with silver
Chloroform-d, 100.0 atom % D
Trichloro(2H)methane
trichloro-deuterio-methane
CHLOROFORM-D >99.95 (ATOM % D) STAB.
CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML)
CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML)
CHLOROFORM-D, 99.8 ATOM % D, STABILIZEDWITH 0.5 WT% SILVER FOIL (CONTAINS 0.03%(
CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS(1PK=10 X 0.75ML
CHLOROFORM-D, 99.9 ATOM % D (CONTAINS 0.03% V/V TMS)
CHLOROFORM-D, 99.8 ATOM % D (CONTAINS 0.03% V/V TMS)
CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS
Chloroform-D,IsotopicPurity>99Atom%D
Chloroform-d, isotopic purity
Chloroform-d,100%D(Isotopic),contains0.03%v/vTMS
Chloroform-d,99.8%(Isotopic),contains0.03%v/vTMS
Chloroform-d, 100 atom % D, packaged in 0.75 ml ampules, for NMR
Chloroform-d, 100.0 atom % D, for NMR
Chloroform-d, 100.0 atom % D, packaged in 0.50 ml ampules, for NMR
Chloroform-d, 99.6+ atom % D, for NMR
Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS, for NMR
Chloroform-d, 99.8 atom % D, for NMR
Chloroform-d, 99.8 atom % D, packaged in 0.75 ml ampules, for NMR
Chloroform-d, 99.8 atom % D, packaged in 1 ml ampules, for NMR
Chloroform-d, 99.8 atom % D, stabilized with silver foil, for NMR
Chloroform-d, 99.8% D, stabilized with silver foil, 1 v/v% TMS, for NMR
Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS, for NMR
Chloroform-d, 99.8+% D, stab. with silver foil, 0.03 v/v% TMS, for NMR
ChloroformD>99.96%10x0.75ml
ChloroformD>99.96%+0.03%tms
ChloroformD>99.8%+0.03%tms
ChloroformD>99.8%10x0.75ml
ChloroformD>99.8%5x10ml
ChloroformD>99.96%10x0.6ml
ChloroformD>99.96%
ChloroformD>99.96%10x0.75ml(+0.03%tms)
Chloroform-d,for NMR,99.8+ atom % D, contains0.03 v/v% TMS