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ChemicalBook--->CAS DataBase List--->150639-33-1

150639-33-1

150639-33-1 Structure

150639-33-1 Structure
IdentificationBack Directory
[Name]

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
[CAS]

150639-33-1
[Synonyms]

2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenylox
(S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.
(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
(S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE
(4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
(S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
(4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile 97%
2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-
2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-
(2Z)-2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-2-[(4S)-4-phenyl-1,3-oxazolidin-2-ylidene]acetonitrile
[Molecular Formula]

C20H17N3O2
[MDL Number]

MFCD00192394
[MOL File]

150639-33-1.mol
[Molecular Weight]

331.37
Chemical PropertiesBack Directory
[Melting point ]

146-148 °C(lit.)
[Boiling point ]

457.5±45.0 °C(Predicted)
[density ]

1.27±0.1 g/cm3(Predicted)
[storage temp. ]

2-8°C
[form ]

solid
[pka]

3.30±0.70(Predicted)
[optical activity]

[α]20/D +364°, c = 1 in chloroform
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
[General Description]

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.
Spectrum DetailBack Directory
[Spectrum Detail]

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE(150639-33-1)IR
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