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ChemicalBook--->CAS DataBase List--->94668-55-0

94668-55-0

94668-55-0 Structure

94668-55-0 Structure
IdentificationBack Directory
[Name]

(N-CROTONYL)-(2R)-BORNANE-10,2-SULTAM
[CAS]

94668-55-0
[Synonyms]

(1S)-N-crotyl-2,10-camphorsultam
(N-CROTONYL)-(2R)-BORNANE-10,2-SULTAM
(R)-(-)-(2-BUTENOYL)-2,10-CAMPHORSULTAM
(E)-1-((3aS,6R,7aR)-8,8-Dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)but-2-en-1-one
2-Buten-1-one, 1-[(3aS,6R,7aR)-tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]-, (2E)-
(N-Crotonyl)-(2R)-bornane-10,2-sultam, (2E)-1-[(3aS,6R,7aR)-Tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]-2-buten-1-one
[Molecular Formula]

C14H21NO3S
[MDL Number]

MFCD00269664
[MOL File]

94668-55-0.mol
[Molecular Weight]

283.39
Chemical PropertiesBack Directory
[Melting point ]

180-184 °C(lit.)
[Boiling point ]

397.2±25.0 °C(Predicted)
[density ]

1.27±0.1 g/cm3(Predicted)
[pka]

-14.19±0.40(Predicted)
[optical activity]

[α]24/D 100°, c = 1 in ethanol
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

(R)-(-)-(2-Butenoyl)-2,10-camphorsultam can be used:
  • In the asymmetric total synthesis of lycopodine via diastereoselective cyclization and intramolecular Mannich cyclization.
  • To prepare (S)-4,4-dichloro-3-methylbutanoic acid, which is utilized as a key intermediate for the total synthesis of dysideaproline E.

Spectrum DetailBack Directory
[Spectrum Detail]

(N-CROTONYL)-(2R)-BORNANE-10,2-SULTAM(94668-55-0)IR
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