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ChemicalBook--->CAS DataBase List--->91159-79-4

91159-79-4

91159-79-4 Structure

91159-79-4 Structure
IdentificationBack Directory
[Name]

4-AZIDOANILINE HYDROCHLORIDE
[CAS]

91159-79-4
[Synonyms]

4-Azidoaniline HCl
4-AZIDOANILINE HYDROCHLORIDE
4-Azidoaniline hydrochloride 97%
4-AMINOPHENYL AZIDE HYDROCHLORIDE
[EINECS(EC#)]

628-425-2
[Molecular Formula]

C6H7ClN4
[MDL Number]

MFCD00043274
[MOL File]

91159-79-4.mol
[Molecular Weight]

170.6
Chemical PropertiesBack Directory
[Melting point ]

165 °C (dec.)(lit.)
[solubility ]

methanol: soluble
[BRN ]

7942921
Safety DataBack Directory
[Hazard Codes ]

F,T
[Risk Statements ]

11-23/24/25-36/37/38
[Safety Statements ]

16-26-33-36/37-45
[RIDADR ]

UN 2926 4.1/PG 2
[WGK Germany ]

3
[F ]

3-8-10
[HazardClass ]

4.1
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

4-Azidoaniline hydrochloride is suitable for use in the preparation of photo-reactive polymers, poly(acrylic acid) having encorporated phenylazido groups. It may be used in the preparation of 1-(4-aminophenyl)-1H-[1,2,3]-triazol-4-ylcarbonyl-Phe-Gly-Phe-Gly-OH. It is suitable for use in the synthesis of photo-reactive polysaccharides.
[Purification Methods]

Purify it in EtOAc with dry HCl gas followed by cold dry Et2O. The free base has m 66o(dec) (MeOH) and the picrate has m 64-65o(dec) (MeOH). The IR has max (Nujol) at 2110cm-1 (N3). [Escher et al. Helv Chim Acta 62 1217 1979, Maffei & Rivolta Gazetta Chim Ital 84 750 1954, Beilstein 12 H 772, 12 IV 1741.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-AZIDOANILINE HYDROCHLORIDE(91159-79-4)1HNMR
4-AZIDOANILINE HYDROCHLORIDE(91159-79-4)FT-IR
4-AZIDOANILINE HYDROCHLORIDE(91159-79-4)Raman
4-AZIDOANILINE HYDROCHLORIDE(91159-79-4)IR
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