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ChemicalBook--->CAS DataBase List--->880262-14-6

880262-14-6

880262-14-6 Structure

880262-14-6 Structure
IdentificationBack Directory
[Name]

((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl](dicyclohexylphosphinite)(1,5-COD)iridium(I)tetrakis(3,5-bis(trifluoromethyl)phenylborate,min.97%
[CAS]

880262-14-6
[Synonyms]

[((4R,5R)-Cy2-Ubaphox)Ir(COD)]BARF
1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)ph
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)
-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)ph
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)
-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl
1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(Ⅰ) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
((4R,5R)-(+)-O-[1-BENZYL-1-(5-METHYL-2-PHENYL-4,5-DIHYDROOXAZOL-4-YL)-2-PHENYLETHYL] (DICYCLOHEXYLPHOSPHINITE)(1,5-COD)IRIDIUM(I) TETRAKIS(3,5-BIS(TRIFLUOROMETHYL)PHENYLBORATE
1,5-Cyclooctadiene{[dibenzyl-((4R,5R)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]-dicyclo-hexylphosphinite KN:KP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl](dicyclohexylphosphinite)(1,5-COD)iridium(I)tetrakis(3,5-bis(trifluoromethyl)phenylborate,min.97%
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97%
((4R,5R)-(+)-O-[1-Benzyl-1-(5-Methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridiuM(I) tetrakis(3,5-bis(trifluoroMethyl)phenylborate (R,R)-[COD]Ir[
[(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazolyl]-2-phenyl-1-(phenylmethyl)ethyl dicyclohexylphosphinite]iridium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[cy2PThrePHOX]
[Molecular Formula]

C37H46NO3P.C32H12BF24.C8H12.Ir
[MDL Number]

MFCD18252665
[MOL File]

880262-14-6.mol
[Molecular Weight]

1747.36
Chemical PropertiesBack Directory
[Melting point ]

160-161°C
[alpha ]

+47° (c 0.1, CHCl3)
[form ]

Powder
[color ]

orange
[Sensitive ]

air sensitive, moisture sensitive, store cold
Hazard InformationBack Directory
[Chemical Properties]

Orange powder
[Uses]

Catalyst for enantioselective hydrogenation of alkenes
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

New class of hydrogenation catalyst which can convert unfunctionalized styrenyl olefins into alkanes with excellent enantioselectivity. Reactions of 880262-14-6
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