Identification | Back Directory | [Name]
DIMETHYL BROMOMALONATE | [CAS]
868-26-8 | [Synonyms]
DIMETHYL BROMOMALONATE Dimethyl 2-bromomalonate Dimethyl bromomalonate ,98% Dimethyl bromomalonate ,96% DiMethyl broMoMalonate, GC 90% Bromomalonic acid dimethyl ester DiMethyl BroMoMalonate, 95.0%(GC) 2-Bromomalonic acid dimethyl ester DIMETHYL BROMOMALONATE, TECH., 90% Dimethyl bromomalonate, 90%, tech. Bromopropanedioic acid dimethyl ester DiMethyl broMoMalonate, tech., 90% 25ML Propanedioic acid, bromo-, dimethyl ester Dimethyl bromomalonate technical grade, 90% | [EINECS(EC#)]
212-775-4 | [Molecular Formula]
C5H7BrO4 | [MDL Number]
MFCD00025865 | [MOL File]
868-26-8.mol | [Molecular Weight]
211.01 |
Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Boiling point ]
105-108 °C11 mm Hg(lit.)
| [density ]
1.601 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.460(lit.)
| [Fp ]
>230 °F
| [form ]
Liquid | [pka]
9.25±0.46(Predicted) | [color ]
Clear colorless to light yellow | [BRN ]
971135 |
Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow liquid | [Uses]
Dimethyl bromomalonate may be used in the enantioselective synthesis of nitrocyclopropanes. | [General Description]
Dimethyl bromomalonate undergoes manganese(III)-promoted free-radical chain addition reaction with olefins, to yield dimethyl 2-bromoalkylmalonates. Organocatalyzed Michael addition of dimethyl bromomalonate to nitrostyrenes to yield synthetically useful nitrocyclopropanes has been reported. Dimethyl bromomalonate reacts readily with arylnitroso compounds to yield the corresponding N-aryl-C,C-dimethoxycarbonylnitrones. |
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Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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