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ChemicalBook--->CAS DataBase List--->848641-69-0

848641-69-0

848641-69-0 Structure

848641-69-0 Structure
IdentificationBack Directory
[Name]

1-Ethyl-3-methylimidazolium diethylphosphate
[CAS]

848641-69-0
[Synonyms]

EMIM DEP
Enim DEP
EMIM(EtO)2PO2
Basionics? LQ 11
Basionics(R) LQ 11
1-Ethyl-3-methylimidazolium diethylphosphate
1-Ethyl-3-methylimidazolium diethyl phosphate >=98.0% (HPLC)
[EINECS(EC#)]

200-100-5
[Molecular Formula]

C10H21N2O4P
[MDL Number]

MFCD09953486
[MOL File]

848641-69-0.mol
Chemical PropertiesBack Directory
[Melting point ]

19-21°C
[Boiling point ]

196℃ at 101.325kPa
[density ]

1.157
[vapor pressure ]

1.2-10.9hPa at 25-60℃
[refractive index ]

n20/D 1.475
[storage temp. ]

Store below +30°C.
[form ]

Liquid
[color ]

Colorless to Yellow to Orange
[PH]

5-7 (200g/l, H2O, 20℃)
[Water Solubility ]

Fully miscible in water.
[Sensitive ]

Moisture Sensitive
[BRN ]

10726450
[LogP]

-0.22 at 25℃ and pH7.5
[CAS DataBase Reference]

848641-69-0
[ECW]

5.8 V
Hazard InformationBack Directory
[Chemical Properties]

Yellow to orange liquid
[Conductivity]

0.84 mS/cm
[Uses]

It finds its application in improving enzymatic hydrolysis of wheat straw and in the enzymatic in situ saccharification of cellulose in aqueous-ionic liquid media.
[Application]

1-Ethyl-3-methylimidazolium diethylphosphate ([C2mim][(C2)2OPO3]) has high biomass solubilization ability due to hydrogen bond basicity and the potential role of cation to rupture the bacterial cell wall. Specifically, one [(C2)2OPO3] anion can interact with two hydroxyl groups of cellulose, which further supports its ability to dissolve biopolymers having OH functionality. Moreover, the cationic imidazolium part of ([C2mim][(C2)2OPO3]) has been shown to interact with negatively charged phospholipid membrane via strong electrostatic interaction to rupture the bacterial membrane[1].
[General Description]

1-Ethyl-3-methylimidazolium diethyl phosphate is a low melting, imidazolium-based ionic liquid, which can dissolve cellulose. The solution of cellulose in EMIM DEP-pyridine mixture is stable in time.
[References]

[1] Dubey S, et al. 1-Ethyl-3-methylimidazolium Diethylphosphate Based Extraction of Bioplastic “Polyhydroxyalkanoates” from Bacteria: Green and Sustainable Approach. ACS Sustainable Chemistry & Engineering, 2017; 6: 766–773.
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

22-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN3265 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29332900
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