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ChemicalBook--->CAS DataBase List--->84030-20-6

84030-20-6

84030-20-6 Structure

84030-20-6 Structure
IdentificationBack Directory
[Name]

1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE
[CAS]

84030-20-6
[Synonyms]

MTBD
CATALYST MTBD
7-Methyl-1,5,7-triazabicyclo[4.4.]dec-5-ene
7-METHYL-1,5,7-TRIAZABICYCLO[4.4.0]DEC-5-ENE
7-Methyl-1,5,7-triazabicyclo[4.4.0]decane-5-ene
7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene>
7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene,95%
7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene 98%
1,3,4,6,7,8-hexahydro-1-methyl-2H-pyrimido(1,2-A)
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMI
1-Methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine
1,2,3,4,6,7-Hexahydro-1-methyl-8H-pyrimido[1,2-a]pyrimidine
1-Methyl-1,2,3,4,7,8-hexahydro-6H-pyrimido[1,2-a]pyrimidine
1-Methyl-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDO[1,2-A]PYRIMIDINE
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE
2H-Pyrimido[1,2-a]pyrimidine, 1,3,4,6,7,8-hexahydro-1-methyl-
1,3,4,6,7,8-Hexahydro-1-methyl-2H-pyrimido[1,2-a]pyrimidine MTBD
7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene, 98%, for synthesis
MTBD, 1,3,4,6,7,8-Hexahydro-1-methyl-2H-pyrimido[1,2-a]pyrimidine
7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene,1,3,4,6,7,8-Hexahydro-1-methyl-2H-pyrimido[1,2-a]pyrimidine, MTBD
[EINECS(EC#)]

281-791-1
[Molecular Formula]

C8H15N3
[MDL Number]

MFCD00043004
[MOL File]

84030-20-6.mol
[Molecular Weight]

153.22
Chemical PropertiesBack Directory
[Boiling point ]

75-79 °C0.1 mm Hg(lit.)
[density ]

1.067 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.537(lit.)
[Fp ]

>230 °F
[storage temp. ]

0-10°C
[form ]

clear liquid
[pka]

14.37±0.20(Predicted)
[color ]

Colorless to Yellow to Orange
[BRN ]

7635759
[InChIKey]

OEBXWWBYZJNKRK-UHFFFAOYSA-N
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3267 8/PG 2
[WGK Germany ]

3
[F ]

10
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29335990
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene may be used in microwave-promoted, palladium-catalyzed C-N bond-forming reactions with aryl/heteroaryl nonaflates and amines. It may be used as strong base to investigate the podand solvents, tris(oxaalkyl)phenylsilanes and tris(oxaalkyl)phosphates.
[General Description]

7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene is a soluble amine base. It forms 1:1 complexes with 4-nitrophenyl[bis(diethylsulfonyl)]methane and phenyl[bis(diethylsulfonyl)]methane and their structures have been studied by FT-IR, 1H NMR and PM5 semiempirical methods. Catalytic performance of 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene for the transesterification of rapseed oil with methanol has been investigated.
Spectrum DetailBack Directory
[Spectrum Detail]

1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE(84030-20-6)1HNMR
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE(84030-20-6)IR
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE(84030-20-6)Raman
1,3,4,6,7,8-HEXAHYDRO-1-METHYL-2H-PYRIMIDOL[1,2-A]PYRIMIDINE(84030-20-6)FT-IR
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