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ChemicalBook--->CAS DataBase List--->8065-48-3

8065-48-3

8065-48-3 Structure

8065-48-3 Structure
IdentificationBack Directory
[Name]

DEMETON
[CAS]

8065-48-3
[Molecular Formula]

C16H38O6P2S4
[MDL Number]

MFCD00466988
[MOL File]

8065-48-3.mol
[Molecular Weight]

516.68
Chemical PropertiesBack Directory
[Appearance]

Demeton is a light brown liquid with an odor of sulfur compounds; freezing/melting point ≤‐13 C
[Boiling point ]

bp2 134°
[density ]

1.1183 g/cm3 (20℃)
[refractive index ]

1.4875 (589.3 nm 20℃)
Hazard InformationBack Directory
[Chemical Properties]

Demeton is a light brown liquid with an odor of sulfur compounds; freezing/melting point ≤‐13 C
[Uses]

Insecticide.
[General Description]

Oily liquid with an amber color and an odor of sulfur. Used as an agricultural insecticide.
[Reactivity Profile]

DEMETON may release sulfur oxides and phosphoric acid. Solvent carrier vapors may travel on ground to ignition source. Avoid strong oxidizers. Avoid mixtures with water or polar solvents, in which sulfur is lost to oxygen, air and light, which cause hydrolysis, alkaline mixtures and oxidizing agents. [EPA, 1998].
[Health Hazard]

DEMETON is a cholinesterase inhibitor. It is readily absorbed through the skinand is extremely toxic. Probable human lethal oral dose is 5-50 mg/kg or 7 drops to 1 teaspoonful for 150 lb. person. Acute dose is believed to be 12 to 20 mg by oral route.
[Fire Hazard]

May release sulfur oxides and phosphoric acid. Solvent carrier vapors may travel on ground to ignition source. Avoid strong oxidizers. Avoid mixtures with water or polar solvents, in which sulfur is lost to oxygen, air and light, which cause hydrolysis, alkaline mixtures and oxidizing agents.
[Potential Exposure]

A potential danger to those involved in the manufacture, formulation, and application of this systemic insecticide and acaricide.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxy- gen if breathing is difficult. Remove and isolate contami- nated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
[Shipping]

UN3278 Organophosphorus compound, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Hazard Technical Name Required, Potential Inhalation Hazard (Special Provision 5). UN3017 Organophosphorus pesticides, liquid, toxic, flammable, flash point not , 23 C, Hazard class: 6.1; Labels: 6.1- Poisonous materials, 3-Flammable liquid. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1- Poisonous materials, Technical Name Required.
[Incompatibilities]

May form explosive mixture with air. Strong oxidizers, strong bases, soluble mercury, other pesticides, and water.
[Waste Disposal]

The thiono-and thiolo-isomers of this mixture are 50% hydrolyzed in 75 minutes and 0.85 min- ute, respectively @ 20℃ and pH 13. At pH 9 and 70 ℃ , the half-life of Demeton is 1.25 hour, but an pH 1-5 it is over 11 hours. Sand and rushed limestone may be added together with a flammable solvent; the resultant mixture may be burned in a furnace with afterburner and alkaline scrubber .In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be dis- posed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
Safety DataBack Directory
[Hazard Codes ]

T+,N
[Risk Statements ]

27/28-50
[Safety Statements ]

28-36/37-45-61
[RIDADR ]

3018
[RTECS ]

TF3150000
[HazardClass ]

6.1(a)
[PackingGroup ]

I
[HS Code ]

29309090
[Toxicity]

LD50 in female, male rats (mg/kg): 2.5, 6.2 orally; 8.2, 14 dermally (Gaines)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

THIOPHOSPHORYL CHLORIDE-->Ethyl 2-hydroxyethyl sulfide
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