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ChemicalBook--->CAS DataBase List--->791616-63-2

791616-63-2

791616-63-2 Structure

791616-63-2 Structure
IdentificationBack Directory
[Name]

(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
[CAS]

791616-63-2
[Synonyms]

1-d:1μ
6-bis[2
(R)-TRIP
SF110001
(11bR)-4-Hydroxy-2
6-triisopropylphenyl)-1
(R)-TRIP or (R)-TRIP PA
2-dioxaphosphepin 4-oxide
6-tris(1-methylethyl)phenyl]dinaphtho[2
1μ-bi-2-naphthol cyclic monophosphate
(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d
(R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate
(S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate
(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'- diyl Hydrogen Phosphate,99%e.e.
(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (HPLC)
(2r)-4-hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide
(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin(R-TRIP)
(11BR)-4-HYDROXY-2,6-BIS[2,4,6-TRIS(1-METHYLETHYL)PHENYL]-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE)
Dinaphtho[2,?1-?d:1',?2'-?f]?[1,?3,?2]?dioxaphosphepin, 4-?hydroxy-?2,?6-?bis[2,?4,?6-?tris(1-?methylethyl)?phenyl]?-?, 4-?oxide, (11bR)?-
(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
[Molecular Formula]

C50H57O4P
[MDL Number]

MFCD10567009
[MOL File]

791616-63-2.mol
[Molecular Weight]

752.98
Chemical PropertiesBack Directory
[Boiling point ]

814.2±75.0 °C(Predicted)
[density ]

1.17±0.1 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[pka]

1.12±0.20(Predicted)
[color ]

white to light-yellow
[InChIKey]

AGQAQYPGJDBIQR-UHFFFAOYSA-N
[SMILES]

O=P1(OC2C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)C=2O1)O
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

29199000
Hazard InformationBack Directory
[Uses]

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
[Definition]

ChEBI: (S)-TRIP is a member of benzenes, a ring assembly and a member of naphthalenes.
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
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