| Identification | Back Directory | [Name]
4-TERT-BUTYLCALIX[6]ARENE | [CAS]
78092-53-2 | [Synonyms]
4-T-BUTYLCALIX[6]ARENE
(contains 5-10% Benzene)
4-TERT-BUTYLCALIX[6]ARENE
P-TERT-BUTYLCALIX[6]ARENE
4-tert-Butylcalix[6]arene,96%
4-tert-Butylcalix[6]arene 95%
4-tert-Butylcalix[6]arene
4-TERT-BUTYLCALIX[6]ARENE (LCAREA)
5,11,17,23,29,35-Hexa-Tert-Butyl-37,38
P-TERT-BUTYLCALIX[6]ARENE FOR SYNTHESIS
HEXA-TERT-BUTYL(HEXAHYDROXY)CALIX[6]ARENE
4-tert-Butylcalix[6]arene (contains 5-10% Benzene)
4-TERT-BUTYLCALIX[6]ARENE (CONTAINS 5-10% BENZENE) 98+%
4-tert-Butylcalix[6]arene (contains 5-10% Benzene)
5,11,17,23,29,35-hexa-tert-butylcalix[6]arene-37,38,39,40,41,42-hexol
5,11,17,23,29,35-HEXA-TERT-BUTYL-37,38,39,40,41,42-HEXAHYDROXYCALIX[6]ARENE
Heptacyclo[31.3.1.13,7.19,13.115,19.121,25.127,31]dotetraconta-1(37),3,5,7(42),9,11,13(41),15,17,19(40),21,23,25(39),27,29,31(38),33,35-octadecaene-37,38,39,40,41,42-hexol,5,11,17,23,29,35-hexakis(1,1-dimethylethyl)
Heptacyclo31.3.1.13,7.19,13.115,19.121,25.127,31dotetraconta-1(37),3,5,7(42),9,11,13(41),15,17,19(40),21,23,25(39),27,29,31(38),33,35-octadecaene-37,38,39,40,41,42-hexol, 5,11,17,23,29,35-hexakis(1,1-dimethylethyl)-
Heptacyclo[31. 3. 1. 13,7. 19,13. 115,19. 121,25. 127,31]dotetraconta-1(37),3,5,7(42),9,11,13(41),15,17,19(40),21,23,25(39),27,29,31(38),33,35-octadecaene-37,38,39,40,41,42-hexol,5,11,17,23,29,35-hexakis(1,1-dimethyle | [Molecular Formula]
C66H84O6 | [MDL Number]
MFCD00075464 | [MOL File]
78092-53-2.mol | [Molecular Weight]
973.37 |
| Chemical Properties | Back Directory | [Appearance]
WHITE FINE CRYSTALLINE POWDER | [Melting point ]
≥300 °C(lit.)
| [Boiling point ]
784.26°C (rough estimate) | [density ]
0.9131 (rough estimate) | [refractive index ]
1.6000 (estimate) | [storage temp. ]
Store below +30°C. | [form ]
powder to crystal | [pka]
9.35±0.20(Predicted) | [color ]
White to Almost white | [Water Solubility ]
<9.73mg/L(temperature not stated) | [λmax]
286nm(CH3CN)(lit.) | [BRN ]
2611918 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE FINE CRYSTALLINE POWDER | [Uses]
Starting material for further derivatization, including halogenation, acylation, and diazo coupling. | [Definition]
ChEBI: 5,11,17,23,29,35-hexa-tert-butylcalix[6]arene-37,38,39,40,41,42-hexol is a substituted calixarene. It derives from a hydride of a calix[6]arene. | [Purification Methods]
It is recrystallised from CHCl3 or CHCl3/MeOH to give a white solid from the mother liquors of the calix[8]arene preparation. The hexa-acetate (Ac2O/H2SO4) crystallises from CHCl3/MeOH with m 360-362o(dec), and the (SiMe3)6 derivative crystallises from CHCl3/MeOH with m 410-412o. Its stability in KOH-xylene is the same as for the 4-tert-butylcalix[4]arene. [Gutsche et al.J Am Chem Soc 103 3782 1981. See also Kluawer in Calixarenes, Vicens & B.hner eds Academic Press 1991, Beilstein 6 IV 7858.] |
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