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ChemicalBook--->CAS DataBase List--->77123-57-0

77123-57-0

77123-57-0 Structure

77123-57-0 Structure
IdentificationBack Directory
[Name]

4-(Trimethylsilyl)ethynylbenzaldehyde
[CAS]

77123-57-0
[Synonyms]

4-(TRIMETHYLSILYL)ETHYNYLBENZALDEHYDE
4-[(TriMethylsilyl)ethynyl]benzaldehy
4-[(Trimethysilyl)-ethynyl]benzaldehyde
4-[2-(triMethylsilyl)ethynyl]benzaldehyde
Benzaldehyde, 4-[(triMethylsilyl)ethynyl]-
4-[(TriMethylsilyl)ethynyl]benzaldehyde 97%
Benzaldehyde, 4-[2-(trimethylsilyl)ethynyl]-
4-[(trimethylsilyl)ethynyl]bezaldehyde min99%(HPLC,GC)
[Molecular Formula]

C12H14OSi
[MDL Number]

MFCD02093765
[MOL File]

77123-57-0.mol
[Molecular Weight]

202.32
Chemical PropertiesBack Directory
[Melting point ]

66-70 °C(lit.)
[Boiling point ]

262.1±32.0 °C(Predicted)
[density ]

0.98±0.1 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

T
[WGK Germany ]

3
[HazardClass ]

IRRITANT
Hazard InformationBack Directory
[Uses]

4-?(Trimethylsilyl)?ethynylbenzaldehyde is a useful reactant for the synthesis of acetylene-?substituted naphthalene diimides in polar solvents.
[General Description]

4-[(Trimethylsilyl)ethynyl]benzaldehyde can be synthesized by reacting 4-bromobenzaldehyde and triphenylphosphine in anhydrous triethylamine with ethynyltrimethylsilane and then with palladium(II) acetate under argon. It can also be prepared by Sonogashira coupling reaction between 4-bromobenzaldehyde and (trimethylsilyl) ethynyl.
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