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ChemicalBook--->CAS DataBase List--->7335-65-1

7335-65-1

7335-65-1 Structure

7335-65-1 Structure
IdentificationBack Directory
[Name]

Hydrazine acetate
[CAS]

7335-65-1
[Synonyms]

HYDRAZINE ACETATE
hydrazinyl acetate
hydrazinium acetate
Hydrazine acetate,99%
Hydrazine acetate 97%
HYDRAZINE MONOACETATE
HYDRAZINE ACETATE SALT
[EINECS(EC#)]

230-845-2
[Molecular Formula]

C2H8N2O2
[MDL Number]

MFCD00013141
[MOL File]

7335-65-1.mol
[Molecular Weight]

92.1
Chemical PropertiesBack Directory
[Appearance]

white to light yellow adhering crystals or powder
[Melting point ]

100-102 °C
[Boiling point ]

171.46°C (rough estimate)
[density ]

1.2495 (rough estimate)
[refractive index ]

1.4350 (estimate)
[storage temp. ]

0-6°C
[form ]

Fine Crystalline Powder
[color ]

White
[InChI]

InChI=1S/C2H4O2.H4N2/c1-2(3)4;1-2/h1H3,(H,3,4);1-2H2
[InChIKey]

YFHNDHXQDJQEEE-UHFFFAOYSA-N
[SMILES]

C(=O)(O)C.NN
[EPA Substance Registry System]

Hydrazine, monoacetate(7335-65-1)
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow adhering crystals or powder
[Uses]

suzuki reaction
[Description]

Hydrazine acetate is an acetate salt of hydrazine. It is used as a reagent to cleavage glycosidic esters and anomeric denitration of carbohydrates. In organic synthesis, it is also used as a building block to prepare various organic derivatives.
[Definition]

Deformylation with hydrazine acetate was slower than that with hydrazine. Approximately 90% and 5% of the formyl group were removed at 50 and 20 °C, respectively, after 5 h. The rate of deformylation with hydrazine acetate is slower than that with hydrazine alone, but hydrazine acetate would be less harmful to a peptide when the peptide hydrazide is recovered from a formylated peptide hydrazide[1].
[References]

[1] K. Hojo. “Acylation of hydrazides with acetic acid and formic acid.” Chemical pharmaceutical bulletin 34 1 (2002): 140–2.
Safety DataBack Directory
[Hazard Codes ]

N-T,N,T
[Risk Statements ]

50/53-45-43-23/24/25-34-46
[Safety Statements ]

61-60-53-45-36/37/39-28-27-26-23
[RIDADR ]

UN 3263
[WGK Germany ]

3
[HS Code ]

29280000
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Hydrazine acetate(7335-65-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Hydrazine acetate(7335-65-1)Raman
Hydrazine acetate(7335-65-1)IR
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