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ChemicalBook--->CAS DataBase List--->71626-11-4

71626-11-4

71626-11-4 Structure

71626-11-4 Structure
IdentificationBack Directory
[Name]

Benalaxyl
[CAS]

71626-11-4
[Synonyms]

m9834
GALBEN
TF 3675
Benalaxyi
BENALAXYL
farmoplant
BENALAXYL 0.92
benalaxyl (bsi,iso)
Benalaxyl 250mg [71626-11-4]
BENALAXYL PESTANAL (METHYL-N-PHENYLACETY
methyln-phenylacetyl-n-2,6-xylyl-dl-alaninate
N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alanine
N-(2,6-DIMETHYLPHENYL)-N-(PHENYLACETYL)-DL-ALANINE ESTER
methyl-N-phenylacetyl-N-2,6-dimethyl phenyl-DL-alaninate
methyln-(2,6-dimethylphenyl)-n-(phenylacetyl)-dl-alaninate
DL-alanine N-(2,6-methylphenyl)-N-(phenylacetyl)-methyl ester
n-(2,6-dimethylphenyl)-n-(phenylacetyl)-dl-alaninemethylester
METHYL2-(N-PHENYLACETYL-N-(2,6-DIMETHYLPHENYL)AMINO)PROPANOATE
n-(2,6-dimethylphenyl)-n-(phenylacetyl)-,methylester,dl-alanin
Alanine, N-(2,6-dimethylphenyl)-N-(phenylacetyl)-, methyl ester
(±)-N-(2,6-Dimethylphenyl)-N-(phenylacetyl)alanine methyl ester
benalaxyl methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate
[EINECS(EC#)]

275-728-7
[Molecular Formula]

C20H23NO3
[MDL Number]

MFCD00143652
[MOL File]

71626-11-4.mol
[Molecular Weight]

325.4
Chemical PropertiesBack Directory
[Melting point ]

78-80°C
[Boiling point ]

463.59°C (rough estimate)
[density ]

1.2700
[vapor pressure ]

6.6 x 10-5 Pa (25 °C)
[refractive index ]

1.5614 (estimate)
[storage temp. ]

0-6°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

neat
[pka]

1.52±0.50(Predicted)
[Water Solubility ]

28.6 mg l-1 (20 °C)
[Merck ]

13,1028
[BRN ]

3001587
[NIST Chemistry Reference]

Benalaxyl(71626-11-4)
[EPA Substance Registry System]

Alanine, N-(2,6-dimethylphenyl)-N-( phenylacetyl)-, methyl ester(71626-11-4)
Hazard InformationBack Directory
[Usage]

An acylamino acid fungicide.
[Uses]

Agricultural fungicide.
[Uses]

An acylamino acid fungicide.
[Uses]

Benalaxyl is used for the control of Oomycetes on a wide range of crops, fruit, flowers, ornamentals and turf.
[Definition]

ChEBI: Methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)alaninate is an alanine derivative that is the N-phenylacetyl derivative of methyl N-(2,6-dimethylphenyl)alaninate It is an alanine derivative, an aromatic amide, a carboxamide and a methyl ester.
[Metabolic pathway]

The fate of 14C-benalaxyl as affected by mancozeb is determined on the surface and in the tissues of grape leaves 7 days after the single foliar application of a mixture with mancozeb. The main oxidative scheme with rat liver microsomes is quite similar to that observed in plants. The only differences are represented by a further hydroxylation on the second ortho methyl group, and only traces of the meta hydroxylation take place on the xylene ring.
[Degradation]

Benalaxyl is stable in aqueous media over a wide pH range but it is hydrolysed in concentrated alkali. Its DT50 at pH 9 and 25 °C is 86 days (PM). It is reasonably stable to sunlight in aqueous solution. When irradiated in solution with UV light (254 nm) it is degraded with a half-life of 55 minutes (Pirisi et al., 1996). Products were compounds 2 and 3 (see Scheme 1) which are common also to metalaxyl and furalaxyl. These were detected in a non-labelled study. Under simulated sunlight its half-life was 167 days.
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

50/53
[Safety Statements ]

60-61
[RIDADR ]

UN 3077
[WGK Germany ]

2
[RTECS ]

AY5993200
[HS Code ]

29242990
[Toxicity]

LD50 in rats (mg/kg): 4200 orally; 1100 i.p.; LC50 (96 hr) in rainbow trout: 3.75 mg/l (Bergamaschi)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Nickel-->Cyclohexane-->2,6-Dimethylaniline-->Methyl propionate-->Methyl acetate-->Phenylacetyl chloride-->methyl N-(2,6-dimethylphenyl)-DL-alaninate
[Preparation Products]

Benalaxyl-M
Spectrum DetailBack Directory
[Spectrum Detail]

Benalaxyl(71626-11-4)MS
Benalaxyl(71626-11-4)1HNMR
Benalaxyl(71626-11-4)13CNMR
Benalaxyl(71626-11-4)IR1
Benalaxyl(71626-11-4)IR2
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