Identification | Back Directory | [Name]
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane | [CAS]
68478-92-2 | [Synonyms]
Karstedt cat KARSTEDT CATALYST platinumvinylsiloxane Karstedt Catalyst Soluti Karstedt Catalyst Solution PLATINUM-DIVINYLTETRAMETHYLDISILOXANE PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX solutioninvinylterminatedpolydimethylsiloxane pt(0)-1,3-divinyl-tetrame-disiloxane compl 0.100 PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisilox 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane platinum PlatinuM(o) 1,3 divinyl-1,1,3,3 tetraMethyldisiloxane Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Platinum-divinyltetramethyldisiloxane complex inxylene 1,3-Divinyl-1,1,3,3-tetramethyl-disiloxane-platinum (0) Platinum-Divinyltetramethyldisiloxane (in Xylene)low colour PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE COMPLEX Platinum,1,3-diethenyl-1,1,3,3-tetramethyldisiloxanecomplexes PLATINUM DIVINYLTETRAMETHYLDISILOXANE COMPLEX, xylene solution PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE LOW COLOR PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE: (2.1-2.4%PT) Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, Pt 2000 ppM PT(0)-1,3-DIVINYL-TETRAME-DISILOXANE COM PL 0.100M IN POLY(DIME-SILOXANE),VINYL PLATINUM(0)-1,3-DIVINYL-TETRAME-DISILOXA NE IN POLY(DI-ME-SILOXANE),VINYLTERMINA PlatinuM (0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, soln. in Isopropanol PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMEDI-SILOXANE COMPLEX, SOLUTION IN XYLENES (PT~2%) PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, in poly(diMethylsiloxane) PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, 20% Pt, Product of UMicore PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution in xylene, Pt ~2 % Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution [in dimethylsiloxane] Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimeth platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimethylsiloxane Karstedt Catalyst Solution Hydrosilylation. Usually supplied in propan-2-ol/ divinyltetramethyldisiloxane Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, solution in vinyl terminated polydimethylsiloxane Platinum(0) - 1,3-Divinyltetramethyldisiloxane Complex (19.0-21.5% as Pt) (contains 1,3-Divinyltetramethyldisiloxane) PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.1 M in poly(diMethylsiloxane), vinyl terMinated PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.05 M in poly(diMethylsiloxane), vinyl terMinated Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes platinum-divinyltetramethyldisiloxane complex karstedt catalyst platinum vinylsiloxane platinumvinylsiloxane Platinum,1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes | [EINECS(EC#)]
270-844-4 | [Molecular Formula]
C8H18OPtSi2 | [MDL Number]
MFCD00151662 | [MOL File]
68478-92-2.mol | [Molecular Weight]
381.48 |
Chemical Properties | Back Directory | [Appearance]
pale yellow solution | [Melting point ]
12-13 °C
| [Boiling point ]
138 °C
| [density ]
0.984 g/mL at 25 °C
| [vapor pressure ]
7 mm Hg ( 21 °C)
| [refractive index ]
1.4954 | [Fp ]
86 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
clear liquid | [color ]
Light yellow to Yellow to Green | [Specific Gravity]
0.984 | [Stability:]
Flammable. Incompatible with reducing agents, oxidizing agents. Contact with water yields hydrogen gas. | [Water Solubility ]
Miscible with toluene, xylene, isopropyl alcohol, double-vinyl silicone oil and vinyl terminated poly(dimethylsiloxane). Immiscible with water. | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Sensitive ]
Moisture Sensitive | [EPA Substance Registry System]
Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes (68478-92-2) |
Hazard Information | Back Directory | [Chemical Properties]
pale yellow solution | [Description]
Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a kind of yellow liquid with a chemical formula of O[Si(CH3)2CH=CH2]2Pt and a molecular weight of 381.48. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution (Pt-DVTMDS) has emerged as a novel organometallic compound with diverse applications in recent scientific research. This compound represents a coordination complex of platinum(0) and divinyl-1,1,3,3-tetramethyldisiloxane complex solution (DVTMDS). It has proven valuable in synthesizing diverse organometallic compounds, including gold(I)-DVTMDS and palladium(II)-DVTMDS. Furthermore, it has played a significant role in investigating chemical reactions, such as the catalytic hydrogenation of aldehydes and ketones theand oxidation of organic compounds. It was used as a precursor of the metallic phase to obtain a highly active electrochemical system Pt/SnO2 catalyst with a low metal load[1].
| [Uses]
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a catalyst in the preparation of phenol functional silanes which are used as adhesion promoters. | [General Description]
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions. |
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