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ChemicalBook--->CAS DataBase List--->6795-23-9

6795-23-9

6795-23-9 Structure

6795-23-9 Structure
IdentificationBack Directory
[Name]

AFLATOXIN M1
[CAS]

6795-23-9
[Synonyms]

AF M1
ALFATOXINM1
Aflatoxin M
AFLATOXIN M1
4-Hydroxyaflato
Aflatoxin M1, >
4-hydroxyaflatoxinb1
aflatoxin m1solution
aflatoxin m1 solution
Aflatoxin M1 Standard
Aflatoxin M1 0.5ug/ml in ACN
ahydro-9a-hydroxy-4-methoxy-
Aflatoxin M1 In Acetonitrile
Aflatoxin M1 standard solution
Aflatoxin M1 Quality Control Sample
aflatoxin M1 from aspergillus flavus
AF M1;Aflatoxin M1;4-Hydroxyaflatoxin B1
38546, AFLATOXIN M STANDARD SOLUTIO
Aflatoxin M1 Solution in Methanol, 10μg/mL
Aflatoxin M1, 98%, from Aspergillus flavus
Aflatoxin M1 Solution, 10 Mg/L, Certan Vial
Aflatoxin M1 Standard Solution, 0.5μg/ml in acetonitrile
2,3,6aα,9aα-Tetrahydro-9a-hydroxy-4-methoxycyclopenta[c]furo[3',2':4,5]furo[2,3-h][1]benzopyran-1,11-dione
(6aR,9aR)-9a-hydroxy-4-methoxy-2,3-dihydrocyclopenta[c]furo[3',2':4,5]furo[2,3-h]chromene-1,11(6aH,9aH)-dione
(6aR-cis)-2,3,6a,9a-tetrahydro-9a-hydroxy-4-methoxycyclopenta[c]furo[3',2':4,5]furo[2,3-h][1]benzopyran-1,11-dione
(6aR,9aR)-2,3,6a,9a-Tetrahydro-9a-hydroxy-4-Methoxy-cyclopenta[c]furo[3',2':4,5]furo[2,3-h][1]benzopyran-1,11-dione
Cyclopenta[c]furo[3',2':4,5]furo[2,3-h][1]benzopyran-1,11-dione, 2,3,6a,9a-tetrahydro-9a-hydroxy-4-methoxy-, (6aR,9aR)-
AFM Aflatoxin M1 (6aR,9aR)-2,3,6a,9a-Tetrahydro-9a-hydroxy-4-methoxycyclopenta[c]furo[3',2':4,5]furo[2,3-h][1]benzopyran-1,11-dione
[EINECS(EC#)]

229-865-4
[Molecular Formula]

C17H12O7
[MDL Number]

MFCD00871812
[MOL File]

6795-23-9.mol
[Molecular Weight]

328.27
Chemical PropertiesBack Directory
[Appearance]

The aflatoxins are a group of molds produced by the fungus Aspergillus flavus. They are natural contaminants of fruits, vegetables, and grains. They are also described as a series of condensed ring heterocyclic compounds. They form colorless to pale yellow crystals. Practically insoluble in water.
[Melting point ]

299℃
[alpha ]

D -280° (c = 0.1 in DMF)
[Boiling point ]

386.03°C (rough estimate)
[density ]

1.3358 (rough estimate)
[refractive index ]

1.4790 (estimate)
[Fp ]

11 °C
[storage temp. ]

2-8°C
[solubility ]

Acetonitrile:Methanol (1:1): 1 mg/ml
[form ]

White to yellow powder.
[pka]

10.76±0.20(Predicted)
[color ]

White to off-white
[BRN ]

1630643
Hazard InformationBack Directory
[Chemical Properties]

Solid
[Uses]

An Aspergillus flavus metabolite. Aflatoxin M1 in milk as a secondary metabolite of the Aflatoxin B1 formed in moldy forages. It is cancerogenic, hepatotoxic, and immunosuppressive in animals and man.
[Definition]

ChEBI: A member of the class of aflatoxins that is aflatoxin B1 in which the hydrogen at position 9a is replaced by a hydroxy group.
[Potential Exposure]

Aflatoxins are a group of toxic metabolites produced by certain types of fungi. Aflatoxins are not commercially manufactured; they are naturally occurring contaminants that are formed by fungi on food during conditions of high temperatures and high humidity. Most human exposure to aflatoxins occurs through ingestion of contaminated food. The estimated amount of aflatoxins that Americans consume daily is estimated to be 0.15 0.50 μg. Grains, peanuts, tree nuts, and cottonseed meal are among the more common foods on which these fungi grow. Meat, eggs, milk, and other edible products from animals that consume aflatoxincontaminated feed may also contain aflatoxins. Aflatoxins can also be breathed in
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. Asfirst aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
[Shipping]

UN3172 Toxins, extracted from living sources, solid or liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
[Waste Disposal]

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Use of oxidizing agents, such as hydrogen peroxide or 5% sodium hypochlorite bleach. Acids and bases may also be used.
[General Description]

Certan Vial
Safety DataBack Directory
[Hazard Codes ]

T+,T,F,Xn
[Risk Statements ]

26/27/28-40-39/23/24/25-23/25-23/24/25-11-36-20/21/22-45
[Safety Statements ]

53-22-36/37/39-45-24-16-7-36-26-36/37-28
[RIDADR ]

UN 3462 6.1/PG 1
[WGK Germany ]

3
[RTECS ]

GY1880000
[F ]

10-23
[HazardClass ]

6.1(a)
[PackingGroup ]

I
[HS Code ]

29322090
[Safety Profile]

Confirmed carcinogen with experimental tumorigenic data. Poison by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also various aflatoxins.
[Toxicity]

LD50 orally in day old Pekin ducklings: 16.6 mg/duckling (Holzapfel, Steyn)
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