Identification | Back Directory | [Name]
1-TRIMETHYLSILOXY-1,3-BUTADIENE | [CAS]
6651-43-0 | [Synonyms]
1-TRIMETHYLSILOXY-1,3-BUTADIENE 1-TRIMETHYLSILYLOXY-1,3-BUTADIENE 4-(Trimethylsiloxy)-1,3-butadiene Trimethyl(1,3-butadienyloxy)silane (1,3-Butadienyloxy)trimethylsilane Trimethylsilyl 1,3-butadienyl ether 1,3-Butadienyl(trimethylsilyl) ether Silane, (1,3-butadienyloxy)trimethyl- 1-(TriMethylsiloxy)-1,3-butadiene 98% (E)-(buta-1,3-dien-1-yloxy)triMethylsilane 1-(Trimethylsilyloxy)-1,3-butadiene, mixture of isomers, 98% 1-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE, 98% , MIXTURE OF ISOMERS | [Molecular Formula]
C7H14OSi | [MDL Number]
MFCD00009647 | [MOL File]
6651-43-0.mol | [Molecular Weight]
142.27 |
Chemical Properties | Back Directory | [Appearance]
clear light yellow liquid | [Boiling point ]
131 °C(lit.)
| [density ]
0.811 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.448(lit.)
| [Fp ]
77 °F
| [storage temp. ]
2-8°C
| [solubility ]
Sol most standard organic solvents. | [form ]
liquid | [Specific Gravity]
0.811 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [BRN ]
1902024 |
Hazard Information | Back Directory | [Chemical Properties]
clear light yellow liquid | [Uses]
Diene used in the Diels-Alder reaction. | [Physical properties]
bp 131 °C, bp 49.5 °C/25 mmHg; d 0.811 g cm?3. | [General Description]
Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods. | [Purification Methods]
Purify it by fractional distillation and collect the fractions with the required 1H NMR. Store it under N2 — it is a flammable and moisture-sensitive liquid. [Caseau et al. Bull Soc Chim Fr 16658 1972, Belge Patent 670,769, Chem Abstr 65 5487d 1966.] |
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Energy Chemical
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